Photo-cleavage of cobalt-carbon bonds of alkylcobalt(III) complexes by iodine with large quantum yields

Shunichi Fukuzumi, Tatsushi Goto, Kunio Ishikawa, Toshio Tanaka

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

Cobalt-carbon bonds of alkylcobalt(III) complexes are readily cleaved by iodine in carbon tetrachloride to yield alkyl iodides via photoinduced electron-transfer radical chain reactions with large quantum yields (e.g., Φ = 7.0 × 103) under low energy irradiation (λ 509 nm).

Original languageEnglish
Pages (from-to)260-261
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number4
DOIs
Publication statusPublished - Jan 1 1989
Externally publishedYes

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Carbon tetrachloride
Carbon Tetrachloride
Iodides
Quantum yield
Cobalt
Iodine
Carbon
Irradiation
Electrons

All Science Journal Classification (ASJC) codes

  • Molecular Medicine

Cite this

Photo-cleavage of cobalt-carbon bonds of alkylcobalt(III) complexes by iodine with large quantum yields. / Fukuzumi, Shunichi; Goto, Tatsushi; Ishikawa, Kunio; Tanaka, Toshio.

In: Journal of the Chemical Society, Chemical Communications, No. 4, 01.01.1989, p. 260-261.

Research output: Contribution to journalArticle

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