Photo-induced long-lived intramolecular electron transfer in a Co valence tautomeric complex

Osamu Sato; Shinya Hayami; Zhong Ze Gu; Kanako Seki; Rie Nakajima; Akira Fujishima

doi:10.1246/cl.2001.874

Photo-induced long-lived intramolecular electron transfer in a Co valence tautomeric complex

Osamu Sato, Shinya Hayami, Zhong Ze Gu, Kanako Seki, Rie Nakajima, Akira Fujishima

Research output: Contribution to journal › Article › peer-review

18 Citations (Scopus)

Abstract

A photo-induced valence tautomerism was observed in a Co complex, [Co^III-LS(phen)(3,5-DBSQ)(3,5-DBCat)]. In this system, visible light illumination induces an electron transfer from 3,5-DBCat to Co^III-LS, producing [Co^II-HS(phen)(3,5-DBSQ)₂]. The resultant photo-induced metastable state could be trapped more than 1 h at 5 K.

Original language	English
Pages (from-to)	874-875
Number of pages	2
Journal	Chemistry Letters
Issue number	9
DOIs	https://doi.org/10.1246/cl.2001.874
Publication status	Published - 2001
Externally published	Yes

All Science Journal Classification (ASJC) codes

Chemistry(all)

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10.1246/cl.2001.874

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title = "Photo-induced long-lived intramolecular electron transfer in a Co valence tautomeric complex",

abstract = "A photo-induced valence tautomerism was observed in a Co complex, [CoIII-LS(phen)(3,5-DBSQ)(3,5-DBCat)]. In this system, visible light illumination induces an electron transfer from 3,5-DBCat to CoIII-LS, producing [CoII-HS(phen)(3,5-DBSQ)2]. The resultant photo-induced metastable state could be trapped more than 1 h at 5 K.",

author = "Osamu Sato and Shinya Hayami and Gu, {Zhong Ze} and Kanako Seki and Rie Nakajima and Akira Fujishima",

year = "2001",

doi = "10.1246/cl.2001.874",

language = "English",

pages = "874--875",

journal = "Chemistry Letters",

issn = "0366-7022",

publisher = "The Chemical Society of Japan",

number = "9",

}

TY - JOUR

T1 - Photo-induced long-lived intramolecular electron transfer in a Co valence tautomeric complex

AU - Sato, Osamu

AU - Hayami, Shinya

AU - Gu, Zhong Ze

AU - Seki, Kanako

AU - Nakajima, Rie

AU - Fujishima, Akira

PY - 2001

Y1 - 2001

N2 - A photo-induced valence tautomerism was observed in a Co complex, [CoIII-LS(phen)(3,5-DBSQ)(3,5-DBCat)]. In this system, visible light illumination induces an electron transfer from 3,5-DBCat to CoIII-LS, producing [CoII-HS(phen)(3,5-DBSQ)2]. The resultant photo-induced metastable state could be trapped more than 1 h at 5 K.

AB - A photo-induced valence tautomerism was observed in a Co complex, [CoIII-LS(phen)(3,5-DBSQ)(3,5-DBCat)]. In this system, visible light illumination induces an electron transfer from 3,5-DBCat to CoIII-LS, producing [CoII-HS(phen)(3,5-DBSQ)2]. The resultant photo-induced metastable state could be trapped more than 1 h at 5 K.

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UR - http://www.scopus.com/inward/citedby.url?scp=0035540038&partnerID=8YFLogxK

U2 - 10.1246/cl.2001.874

DO - 10.1246/cl.2001.874

M3 - Article

AN - SCOPUS:0035540038

SN - 0366-7022

SP - 874

EP - 875

JO - Chemistry Letters

JF - Chemistry Letters

IS - 9

ER -

Photo-induced long-lived intramolecular electron transfer in a Co valence tautomeric complex

Abstract

All Science Journal Classification (ASJC) codes

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