Photo-swing extraction system for the separation of lanthanide using a pyrene group-containing thermosensitive polymer combined with carbon nanotubes

Syouhei Nishihama, Seitaro Takayama, Kazuharu Yoshizuka, Tsuyohiko Fujigaya, Naotoshi Nakashima

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

A novel photo-swing extraction system for lanthanide separation was developed using a copolymer of acid phosphoxy ethyl methacrylate (Phosmer-M), N-isopropylacrylamide (NIPAM), and (1-pyrene)methyl methacrylate (Phosmer-M/NIPAM/PyMMA). Single-walled carbon nanotubes (CNTs) were successfully dispersed in the Phosmer-M/NIPAM/PyMMA as a result of the π-π interactions of the pyrene groups. The phase transition of the copolymer was successfully induced via photo-irradiation as a result of heat generation by the CNTs. The extraction of Eu(III) was increased by the photo-irradiation because of changes in volume and hydrophobicity of the copolymer. Separation of the lanthanides was improved by the photo-irradiation, especially for the combination of Eu(III)/Sc(III).

Original languageEnglish
Pages (from-to)2492-2500
Number of pages9
JournalSeparation Science and Technology (Philadelphia)
Volume51
Issue number15-16
DOIs
Publication statusPublished - Nov 1 2016

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Lanthanoid Series Elements
Carbon Nanotubes
Pyrene
Rare earth elements
Carbon nanotubes
Polymers
Methacrylates
Copolymers
Irradiation
Heat generation
Single-walled carbon nanotubes (SWCN)
Hydrophobicity
Phase transitions
Acids
N-isopropylacrylamide
pyrene
Phosmer-M adhesion promoting monomer

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Chemical Engineering(all)
  • Process Chemistry and Technology
  • Filtration and Separation

Cite this

Photo-swing extraction system for the separation of lanthanide using a pyrene group-containing thermosensitive polymer combined with carbon nanotubes. / Nishihama, Syouhei; Takayama, Seitaro; Yoshizuka, Kazuharu; Fujigaya, Tsuyohiko; Nakashima, Naotoshi.

In: Separation Science and Technology (Philadelphia), Vol. 51, No. 15-16, 01.11.2016, p. 2492-2500.

Research output: Contribution to journalArticle

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