Photocatalytic alkene reduction by a B12-TiO2 hybrid catalyst coupled with C-F bond cleavage for

Gem -difluoroolefin synthesis

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11 Citations (Scopus)

Abstract

Photocatalytic syntheses of gem-difluoroolefins were performed using the B12-TiO2 hybrid catalyst during the CC bond reduction of α-trifluoromethyl styrenes with C-F bond cleavage at room temperature under nitrogen. The gem-difluoroolefins were used as synthetic precursors for fluorinated cyclopropanes.

Original languageEnglish
Pages (from-to)9478-9481
Number of pages4
JournalChemical Communications
Volume53
Issue number68
DOIs
Publication statusPublished - 2017

Fingerprint

Gems
Alkenes
Olefins
Styrenes
Cyclopropanes
Catalysts
Styrene
Nitrogen
Temperature

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Cite this

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title = "Photocatalytic alkene reduction by a B12-TiO2 hybrid catalyst coupled with C-F bond cleavage for: Gem -difluoroolefin synthesis",
abstract = "Photocatalytic syntheses of gem-difluoroolefins were performed using the B12-TiO2 hybrid catalyst during the CC bond reduction of α-trifluoromethyl styrenes with C-F bond cleavage at room temperature under nitrogen. The gem-difluoroolefins were used as synthetic precursors for fluorinated cyclopropanes.",
author = "Hui Tian and Hisashi Shimakoshi and Kenji Imamura and Yoshihito Shiota and Kazunari Yoshizawa and Yoshio Hisaeda",
year = "2017",
doi = "10.1039/c7cc04377e",
language = "English",
volume = "53",
pages = "9478--9481",
journal = "Chemical Communications",
issn = "1359-7345",
publisher = "Royal Society of Chemistry",
number = "68",

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T2 - Gem -difluoroolefin synthesis

AU - Tian, Hui

AU - Shimakoshi, Hisashi

AU - Imamura, Kenji

AU - Shiota, Yoshihito

AU - Yoshizawa, Kazunari

AU - Hisaeda, Yoshio

PY - 2017

Y1 - 2017

N2 - Photocatalytic syntheses of gem-difluoroolefins were performed using the B12-TiO2 hybrid catalyst during the CC bond reduction of α-trifluoromethyl styrenes with C-F bond cleavage at room temperature under nitrogen. The gem-difluoroolefins were used as synthetic precursors for fluorinated cyclopropanes.

AB - Photocatalytic syntheses of gem-difluoroolefins were performed using the B12-TiO2 hybrid catalyst during the CC bond reduction of α-trifluoromethyl styrenes with C-F bond cleavage at room temperature under nitrogen. The gem-difluoroolefins were used as synthetic precursors for fluorinated cyclopropanes.

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DO - 10.1039/c7cc04377e

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