Photochemical H2 evolution from water catalyzed by a dichloro(diphenylbipyridine)platinum(ii) derivative tethered to multiple viologen acceptors

Kyoji Kitamoto, Ken Sakai

Research output: Contribution to journalArticle

16 Citations (Scopus)

Abstract

A new single-component photocatalyst for the reduction of water to H2, a dichloro(dpbpy)platinum(ii) derivative (dpbpy = 4,4′-diphenyl-2,2′-bipyridine) tethered to four pendant viologen acceptors (1), is shown to exhibit twice higher photocatalytic efficiency than the previously reported dichloro(bpy)-platinum(ii) analog (2; bpy = 2,2′-bipyridine), consistent with the higher absorptivity of 1 at the metal-to-ligand charge transfer (1MLCT) band due to the larger π-conjugation in dpbpy relative to bpy.

Original languageEnglish
Pages (from-to)1385-1388
Number of pages4
JournalChemical Communications
Volume52
Issue number7
DOIs
Publication statusPublished - Jan 25 2016

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All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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