Photochemical reactions of ketones to synthesize gold nanorods

Koji Nishioka, Yasuro Niidome, Sunao Yamada

    Research output: Contribution to journalArticlepeer-review

    56 Citations (Scopus)

    Abstract

    Photochemical synthesis of gold nanorods (NRs) in a micellar solution of hexadecyltrimethylammonium bromide (CTAB) was triggered by photoreactions of ketones. Photoexcitation of gold ions and silver bromide clusters ((AgBr) n) in the absence of ketones did not produce NRs. The initial products of the photoirradiation were probably ketyl radicals, which then initiated reactions to form NRs. NRs formed in darkness, if the reaction solutions were irradiated by UV light for a few minutes, thus indicating that the photochemical products catalyzed NR-formation.

    Original languageEnglish
    Pages (from-to)10353-10356
    Number of pages4
    JournalLangmuir
    Volume23
    Issue number20
    DOIs
    Publication statusPublished - Sep 25 2007

    All Science Journal Classification (ASJC) codes

    • Materials Science(all)
    • Condensed Matter Physics
    • Surfaces and Interfaces
    • Spectroscopy
    • Electrochemistry

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