Photochemical reduction of water to hydrogen catalyzed by mixed-valent tetranuclear platinum complex

Ken Sakai, Kazuko Matsumoto

Research output: Contribution to journalArticle

34 Citations (Scopus)

Abstract

Mixed-valent tetranuclear platinum complex, [Pt4(NH3)8(C4H6NO)4]n+ (n = 4, 5, 6, 8 ; C4H6NO = deprotonat-ed -pyrrolidone idone), is used as a homogeneous hydrogen-producing catalyst in a photochemical model system containing EDTA as an electron donor, Ru(bpy)3 2+ as a sensitizer and methyl-viologen (MV2+) as an electron relay.

Original languageEnglish
Pages (from-to)169-172
Number of pages4
JournalJournal of Coordination Chemistry
Volume18
Issue number1-3
DOIs
Publication statusPublished - Sep 1 1988
Externally publishedYes

Fingerprint

Platinum
Hydrogen
platinum
Pyrrolidinones
Paraquat
Electrons
Water
ethylenediaminetetraacetic acids
Ethylenediaminetetraacetic acid
relay
hydrogen
Edetic Acid
water
electrons
catalysts
Catalysts
tris(2,2'-bipyridine)ruthenium II

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Materials Chemistry

Cite this

Photochemical reduction of water to hydrogen catalyzed by mixed-valent tetranuclear platinum complex. / Sakai, Ken; Matsumoto, Kazuko.

In: Journal of Coordination Chemistry, Vol. 18, No. 1-3, 01.09.1988, p. 169-172.

Research output: Contribution to journalArticle

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