Photochemical reduction of water to hydrogen catalyzed by mixed-valent tetranuclear platinum complex

Ken Sakai; Kazuko Matsumoto

doi:10.1080/00958978808080702

Photochemical reduction of water to hydrogen catalyzed by mixed-valent tetranuclear platinum complex

Ken Sakai, Kazuko Matsumoto

Research output: Contribution to journal › Article › peer-review

34 Citations (Scopus)

Abstract

Mixed-valent tetranuclear platinum complex, [Pt₄(NH₃)₈(C₄H₆NO)₄]ⁿ⁺ (n = 4, 5, 6, 8 ; C₄H₆NO = deprotonat-ed -pyrrolidone idone), is used as a homogeneous hydrogen-producing catalyst in a photochemical model system containing EDTA as an electron donor, Ru(bpy)₃ ²⁺ as a sensitizer and methyl-viologen (MV²⁺) as an electron relay.

Original language	English
Pages (from-to)	169-172
Number of pages	4
Journal	Journal of Coordination Chemistry
Volume	18
Issue number	1-3
DOIs	https://doi.org/10.1080/00958978808080702
Publication status	Published - Sep 1 1988
Externally published	Yes

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry
Materials Chemistry

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10.1080/00958978808080702

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title = "Photochemical reduction of water to hydrogen catalyzed by mixed-valent tetranuclear platinum complex",

abstract = "Mixed-valent tetranuclear platinum complex, [Pt4(NH3)8(C4H6NO)4]n+ (n = 4, 5, 6, 8 ; C4H6NO = deprotonat-ed -pyrrolidone idone), is used as a homogeneous hydrogen-producing catalyst in a photochemical model system containing EDTA as an electron donor, Ru(bpy)3 2+ as a sensitizer and methyl-viologen (MV2+) as an electron relay.",

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AB - Mixed-valent tetranuclear platinum complex, [Pt4(NH3)8(C4H6NO)4]n+ (n = 4, 5, 6, 8 ; C4H6NO = deprotonat-ed -pyrrolidone idone), is used as a homogeneous hydrogen-producing catalyst in a photochemical model system containing EDTA as an electron donor, Ru(bpy)3 2+ as a sensitizer and methyl-viologen (MV2+) as an electron relay.

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