Photochemical Water Oxidation Catalyzed by a Water-Soluble Copper Phthalocyanine Complex

Ryota Terao; Takashi Nakazono; Alexander Rene Parent; Ken Sakai

doi:10.1002/cplu.201600263

Photochemical Water Oxidation Catalyzed by a Water-Soluble Copper Phthalocyanine Complex

Ryota Terao, Takashi Nakazono, Alexander Rene Parent, Ken Sakai

Inorganic and Analytical Chemistry

Research output: Contribution to journal › Article › peer-review

51 Citations (Scopus)

Abstract

Copper tetrasulfonatophthalocyanine (CuPcTS) is reported to serve as a catalyst for photochemical water oxidation via a radical coupling mechanism. Chloride greatly inhibits the water oxidation rate as a result of axial chloride binding to CuPcTS, preventing formation of the Cu oxyl or hydroxyl intermediate required for O−O bond formation.

Original language	English
Pages (from-to)	1064-1067
Number of pages	4
Journal	ChemPlusChem
Volume	81
Issue number	10
DOIs	https://doi.org/10.1002/cplu.201600263
Publication status	Published - Oct 1 2016

All Science Journal Classification (ASJC) codes

Chemistry(all)

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10.1002/cplu.201600263

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title = "Photochemical Water Oxidation Catalyzed by a Water-Soluble Copper Phthalocyanine Complex",

abstract = "Copper tetrasulfonatophthalocyanine (CuPcTS) is reported to serve as a catalyst for photochemical water oxidation via a radical coupling mechanism. Chloride greatly inhibits the water oxidation rate as a result of axial chloride binding to CuPcTS, preventing formation of the Cu oxyl or hydroxyl intermediate required for O−O bond formation.",

author = "Ryota Terao and Takashi Nakazono and Parent, {Alexander Rene} and Ken Sakai",

year = "2016",

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AU - Terao, Ryota

AU - Nakazono, Takashi

AU - Parent, Alexander Rene

AU - Sakai, Ken

PY - 2016/10/1

Y1 - 2016/10/1

N2 - Copper tetrasulfonatophthalocyanine (CuPcTS) is reported to serve as a catalyst for photochemical water oxidation via a radical coupling mechanism. Chloride greatly inhibits the water oxidation rate as a result of axial chloride binding to CuPcTS, preventing formation of the Cu oxyl or hydroxyl intermediate required for O−O bond formation.

AB - Copper tetrasulfonatophthalocyanine (CuPcTS) is reported to serve as a catalyst for photochemical water oxidation via a radical coupling mechanism. Chloride greatly inhibits the water oxidation rate as a result of axial chloride binding to CuPcTS, preventing formation of the Cu oxyl or hydroxyl intermediate required for O−O bond formation.

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DO - 10.1002/cplu.201600263

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JO - ChemPlusChem

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Photochemical Water Oxidation Catalyzed by a Water-Soluble Copper Phthalocyanine Complex

Abstract

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