Photochemical Water Oxidation Catalyzed by a Water-Soluble Copper Phthalocyanine Complex

Ryota Terao, Takashi Nakazono, Alexander Rene Parent, Ken Sakai

Research output: Contribution to journalArticle

24 Citations (Scopus)

Abstract

Copper tetrasulfonatophthalocyanine (CuPcTS) is reported to serve as a catalyst for photochemical water oxidation via a radical coupling mechanism. Chloride greatly inhibits the water oxidation rate as a result of axial chloride binding to CuPcTS, preventing formation of the Cu oxyl or hydroxyl intermediate required for O−O bond formation.

Original languageEnglish
Pages (from-to)1064-1067
Number of pages4
JournalChemPlusChem
Volume81
Issue number10
DOIs
Publication statusPublished - Oct 1 2016

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Chlorides
Oxidation
Water
Hydroxyl Radical
Copper
Catalysts
copper phthalocyanine

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

Cite this

Photochemical Water Oxidation Catalyzed by a Water-Soluble Copper Phthalocyanine Complex. / Terao, Ryota; Nakazono, Takashi; Parent, Alexander Rene; Sakai, Ken.

In: ChemPlusChem, Vol. 81, No. 10, 01.10.2016, p. 1064-1067.

Research output: Contribution to journalArticle

Terao, Ryota ; Nakazono, Takashi ; Parent, Alexander Rene ; Sakai, Ken. / Photochemical Water Oxidation Catalyzed by a Water-Soluble Copper Phthalocyanine Complex. In: ChemPlusChem. 2016 ; Vol. 81, No. 10. pp. 1064-1067.
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