Photocontrol of micellar catalysis

Seiji Shinkai; Katsuta Matsuo; Michiko Sato; Takaaki Sone; Osamu Manabe

doi:10.1016/S0040-4039(01)90335-1

Photocontrol of micellar catalysis

Seiji Shinkai, Katsuta Matsuo, Michiko Sato, Takaaki Sone, Osamu Manabe

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

A photoresponsive surfactant with a cationic azobenzene head group (I) was synthesized. It was demonstrated that by mixing (I) with a conventional cationic micelle the rate of the micelle-catalyzed reaction (base-catalyzed proton abstraction from benzoin) can be controlled by light. The origin of the photocontrol was accounted for by the difference in the partitioning of trans-(I) and cis-(I) in the micelle phase.

Original language	English
Pages (from-to)	1409-1412
Number of pages	4
Journal	Tetrahedron Letters
Volume	22
Issue number	15
DOIs	https://doi.org/10.1016/S0040-4039(01)90335-1
Publication status	Published - 1981
Externally published	Yes

All Science Journal Classification (ASJC) codes

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/S0040-4039(01)90335-1

Cite this

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title = "Photocontrol of micellar catalysis",

abstract = "A photoresponsive surfactant with a cationic azobenzene head group (I) was synthesized. It was demonstrated that by mixing (I) with a conventional cationic micelle the rate of the micelle-catalyzed reaction (base-catalyzed proton abstraction from benzoin) can be controlled by light. The origin of the photocontrol was accounted for by the difference in the partitioning of trans-(I) and cis-(I) in the micelle phase.",

author = "Seiji Shinkai and Katsuta Matsuo and Michiko Sato and Takaaki Sone and Osamu Manabe",

year = "1981",

doi = "10.1016/S0040-4039(01)90335-1",

language = "English",

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pages = "1409--1412",

journal = "Tetrahedron Letters",

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TY - JOUR

T1 - Photocontrol of micellar catalysis

AU - Shinkai, Seiji

AU - Matsuo, Katsuta

AU - Sato, Michiko

AU - Sone, Takaaki

AU - Manabe, Osamu

PY - 1981

Y1 - 1981

N2 - A photoresponsive surfactant with a cationic azobenzene head group (I) was synthesized. It was demonstrated that by mixing (I) with a conventional cationic micelle the rate of the micelle-catalyzed reaction (base-catalyzed proton abstraction from benzoin) can be controlled by light. The origin of the photocontrol was accounted for by the difference in the partitioning of trans-(I) and cis-(I) in the micelle phase.

AB - A photoresponsive surfactant with a cationic azobenzene head group (I) was synthesized. It was demonstrated that by mixing (I) with a conventional cationic micelle the rate of the micelle-catalyzed reaction (base-catalyzed proton abstraction from benzoin) can be controlled by light. The origin of the photocontrol was accounted for by the difference in the partitioning of trans-(I) and cis-(I) in the micelle phase.

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UR - http://www.scopus.com/inward/citedby.url?scp=33748874336&partnerID=8YFLogxK

U2 - 10.1016/S0040-4039(01)90335-1

DO - 10.1016/S0040-4039(01)90335-1

M3 - Article

AN - SCOPUS:33748874336

SN - 0040-4039

VL - 22

SP - 1409

EP - 1412

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 15

ER -

Photocontrol of micellar catalysis

Abstract

All Science Journal Classification (ASJC) codes

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