Photodepletion spectroscopy on charge resonance band of (C6H6)2+ and (C6H6)3+

Kazuhiko Ohashi; Nobuyuki Nishi

doi:10.1021/j100186a030

Photodepletion spectroscopy on charge resonance band of (C₆H₆)₂⁺ and (C₆H₆)₃⁺

Kazuhiko Ohashi, Nobuyuki Nishi

Physical Chemistry

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46 Citations (Scopus)

Abstract

Photodepletion spectra of (C₆H₆)₂⁺ and (C₆H₆)₃⁺ are obtained from the depletion yields of the parent ions as functions of photodissociation wavelengths of 750-970 nm. The spectrum of (C₆H₆)₂⁺ shows a broad and featureless band with a maximum at ≈920 nm and an (estimated) width of ≈2000 cm^-1. The spectrum of (C₆H₆)₃⁺ shows a similar absorption to the (C₆H₆)₂⁺ band, suggesting that the (C₆H₆)₃⁺ band is due to the charge resonance transition in the dimer ion subunit.

Original language	English
Pages (from-to)	2931-2932
Number of pages	2
Journal	Journal of physical chemistry
Volume	96
Issue number	7
DOIs	https://doi.org/10.1021/j100186a030
Publication status	Published - Jan 1 1992

All Science Journal Classification (ASJC) codes

Engineering(all)
Physical and Theoretical Chemistry

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10.1021/j100186a030

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title = "Photodepletion spectroscopy on charge resonance band of (C6H6)2+ and (C6H6)3+",

abstract = "Photodepletion spectra of (C6H6)2+ and (C6H6)3+ are obtained from the depletion yields of the parent ions as functions of photodissociation wavelengths of 750-970 nm. The spectrum of (C6H6)2+ shows a broad and featureless band with a maximum at ≈920 nm and an (estimated) width of ≈2000 cm-1. The spectrum of (C6H6)3+ shows a similar absorption to the (C6H6)2+ band, suggesting that the (C6H6)3+ band is due to the charge resonance transition in the dimer ion subunit.",

author = "Kazuhiko Ohashi and Nobuyuki Nishi",

year = "1992",

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doi = "10.1021/j100186a030",

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T1 - Photodepletion spectroscopy on charge resonance band of (C6H6)2+ and (C6H6)3+

AU - Ohashi, Kazuhiko

AU - Nishi, Nobuyuki

PY - 1992/1/1

Y1 - 1992/1/1

N2 - Photodepletion spectra of (C6H6)2+ and (C6H6)3+ are obtained from the depletion yields of the parent ions as functions of photodissociation wavelengths of 750-970 nm. The spectrum of (C6H6)2+ shows a broad and featureless band with a maximum at ≈920 nm and an (estimated) width of ≈2000 cm-1. The spectrum of (C6H6)3+ shows a similar absorption to the (C6H6)2+ band, suggesting that the (C6H6)3+ band is due to the charge resonance transition in the dimer ion subunit.

AB - Photodepletion spectra of (C6H6)2+ and (C6H6)3+ are obtained from the depletion yields of the parent ions as functions of photodissociation wavelengths of 750-970 nm. The spectrum of (C6H6)2+ shows a broad and featureless band with a maximum at ≈920 nm and an (estimated) width of ≈2000 cm-1. The spectrum of (C6H6)3+ shows a similar absorption to the (C6H6)2+ band, suggesting that the (C6H6)3+ band is due to the charge resonance transition in the dimer ion subunit.

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JF - Journal of Physical Chemistry

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Photodepletion spectroscopy on charge resonance band of (C₆H₆)₂⁺ and (C₆H₆)₃⁺

Abstract

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