Photodissociation of polycrystalline and amorphous water ice films at 157 and 193 nm

Akihiro Yabushita, Daichi Kanda, Noboru Kawanaka, Masahiro Kawasaki, Michael N.R. Ashfold

Research output: Contribution to journalArticle

38 Citations (Scopus)

Abstract

The photodissociation dynamics of amorphous solid water (ASW) films and polycrystalline ice (PCI) films at a substrate temperature of 100 K have been investigated by analyzing the time-of-flight (TOF) mass spectra of photofragment hydrogen atoms at 157 and 193 nm. For PCI films, the TOF spectrum recorded at 157 nm could be characterized by a combination of three different (fast, medium, and slow) Maxwell-Boltzmann energy distributions, while that measured at 193 nm can be fitted in terms of solely a fast component. For ASW films, the TOF spectra measured at 157 and 193 nm were both dominated by the slow component, indicating that the photofragment H atoms are accommodated to the substrate temperature by collisions. H atom formation at 193 nm is attributed to the photodissociation of water species on the ice surface, while at 157 nm it is ascribable to a mixture of surface and bulk photodissociations. Atmospheric implications in the high latitude mesopause region of the Earth are discussed.

Original languageEnglish
Article number133406
JournalJournal of Chemical Physics
Volume125
Issue number13
DOIs
Publication statusPublished - Oct 12 2006
Externally publishedYes

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Photodissociation
Ice
photodissociation
ice
Water
Atoms
water
mesopause
Substrates
polar regions
mass spectra
atoms
Hydrogen
hydrogen atoms
energy distribution
Earth (planet)
Temperature
collisions
temperature

All Science Journal Classification (ASJC) codes

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

Cite this

Photodissociation of polycrystalline and amorphous water ice films at 157 and 193 nm. / Yabushita, Akihiro; Kanda, Daichi; Kawanaka, Noboru; Kawasaki, Masahiro; Ashfold, Michael N.R.

In: Journal of Chemical Physics, Vol. 125, No. 13, 133406, 12.10.2006.

Research output: Contribution to journalArticle

Yabushita, Akihiro ; Kanda, Daichi ; Kawanaka, Noboru ; Kawasaki, Masahiro ; Ashfold, Michael N.R. / Photodissociation of polycrystalline and amorphous water ice films at 157 and 193 nm. In: Journal of Chemical Physics. 2006 ; Vol. 125, No. 13.
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