Photodissociation spectroscopy of (C6H6)2 PLU

Kazuhiko Ohashi, Yasuhiro Nakai, Takeshi Shibata, Nobuyuki Nishi

Research output: Contribution to journalArticle

44 Citations (Scopus)

Abstract

The photodissociation spectrum of (C6H6)2 PLU is obtained from the yields of fragment C6H6 PLU ion as a function of photodissociation wavelength in the 400-1400 nm region. Two bands at 440 and 580 nm are attributed to the C ← X and the B ← X local excitation (LE) bands, respectively. Both the most intense band at 920 nm and relatively weak one at 1160 nm are assigned to charge resonance (CR) bands. The red-shift of the B ← B band from the of C6H6 PLU and the cross section at the CR bands much larger than those at the LE bands are consistent with a sandwich structure for (C6H6)2 PLU. The appearance of the two CR bands is explained on the basis of displaced sandwich structures for (C6H6)2 PLU.

Original languageEnglish
Pages (from-to)3-14
Number of pages12
JournalLaser Chemistry
Volume14
Issue number1-3
Publication statusPublished - 1994

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Photodissociation
photodissociation
Spectrum Analysis
Sandwich structures
Spectroscopy
Ions
spectroscopy
sandwich structures
Wavelength
Am 580
red shift
excitation
fragments
cross sections

All Science Journal Classification (ASJC) codes

  • Chemical Engineering(all)
  • Electronic, Optical and Magnetic Materials

Cite this

Ohashi, K., Nakai, Y., Shibata, T., & Nishi, N. (1994). Photodissociation spectroscopy of (C6H6)2 PLU . Laser Chemistry, 14(1-3), 3-14.

Photodissociation spectroscopy of (C6H6)2 PLU . / Ohashi, Kazuhiko; Nakai, Yasuhiro; Shibata, Takeshi; Nishi, Nobuyuki.

In: Laser Chemistry, Vol. 14, No. 1-3, 1994, p. 3-14.

Research output: Contribution to journalArticle

Ohashi, K, Nakai, Y, Shibata, T & Nishi, N 1994, 'Photodissociation spectroscopy of (C6H6)2 PLU ', Laser Chemistry, vol. 14, no. 1-3, pp. 3-14.
Ohashi K, Nakai Y, Shibata T, Nishi N. Photodissociation spectroscopy of (C6H6)2 PLU . Laser Chemistry. 1994;14(1-3):3-14.
Ohashi, Kazuhiko ; Nakai, Yasuhiro ; Shibata, Takeshi ; Nishi, Nobuyuki. / Photodissociation spectroscopy of (C6H6)2 PLU . In: Laser Chemistry. 1994 ; Vol. 14, No. 1-3. pp. 3-14.
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