Photodissociation spectroscopy of (C6H6)2PLU

Kazuhiko Ohashi; Yasuhiro Nakai; Takeshi Shibata; Nobuyuki Nishi

doi:10.1155/1994/52450

Photodissociation spectroscopy of (C₆H₆)₂^PLU

Kazuhiko Ohashi, Yasuhiro Nakai, Takeshi Shibata, Nobuyuki Nishi

Physical Chemistry

Research output: Contribution to journal › Article › peer-review

45 Citations (Scopus)

Abstract

The photodissociation spectrum of (C₆H₆)₂^PLU is obtained from the yields of fragment C₆H₆^PLU ion as a function of photodissociation wavelength in the 400-1400 nm region. Two bands at 440 and 580 nm are attributed to the C ← X and the B ← X local excitation (LE) bands, respectively. Both the most intense band at 920 nm and relatively weak one at 1160 nm are assigned to charge resonance (CR) bands. The red-shift of the B ← B band from the of C₆H₆^PLU and the cross section at the CR bands much larger than those at the LE bands are consistent with a sandwich structure for (C₆H₆)₂^PLU. The appearance of the two CR bands is explained on the basis of displaced sandwich structures for (C₆H₆)₂^PLU.

Original language	English
Pages (from-to)	3-14
Number of pages	12
Journal	Laser Chemistry
Volume	14
Issue number	1-3
DOIs	https://doi.org/10.1155/1994/52450
Publication status	Published - 1994

All Science Journal Classification (ASJC) codes

Atomic and Molecular Physics, and Optics
Biochemistry
Spectroscopy

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title = "Photodissociation spectroscopy of (C6H6)2PLU",

abstract = "The photodissociation spectrum of (C6H6)2PLU is obtained from the yields of fragment C6H6PLU ion as a function of photodissociation wavelength in the 400-1400 nm region. Two bands at 440 and 580 nm are attributed to the C ← X and the B ← X local excitation (LE) bands, respectively. Both the most intense band at 920 nm and relatively weak one at 1160 nm are assigned to charge resonance (CR) bands. The red-shift of the B ← B band from the of C6H6PLU and the cross section at the CR bands much larger than those at the LE bands are consistent with a sandwich structure for (C6H6)2PLU. The appearance of the two CR bands is explained on the basis of displaced sandwich structures for (C6H6)2PLU.",

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journal = "Laser Chemistry",

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T1 - Photodissociation spectroscopy of (C6H6)2PLU

AU - Ohashi, Kazuhiko

AU - Nakai, Yasuhiro

AU - Shibata, Takeshi

AU - Nishi, Nobuyuki

PY - 1994

Y1 - 1994

N2 - The photodissociation spectrum of (C6H6)2PLU is obtained from the yields of fragment C6H6PLU ion as a function of photodissociation wavelength in the 400-1400 nm region. Two bands at 440 and 580 nm are attributed to the C ← X and the B ← X local excitation (LE) bands, respectively. Both the most intense band at 920 nm and relatively weak one at 1160 nm are assigned to charge resonance (CR) bands. The red-shift of the B ← B band from the of C6H6PLU and the cross section at the CR bands much larger than those at the LE bands are consistent with a sandwich structure for (C6H6)2PLU. The appearance of the two CR bands is explained on the basis of displaced sandwich structures for (C6H6)2PLU.

AB - The photodissociation spectrum of (C6H6)2PLU is obtained from the yields of fragment C6H6PLU ion as a function of photodissociation wavelength in the 400-1400 nm region. Two bands at 440 and 580 nm are attributed to the C ← X and the B ← X local excitation (LE) bands, respectively. Both the most intense band at 920 nm and relatively weak one at 1160 nm are assigned to charge resonance (CR) bands. The red-shift of the B ← B band from the of C6H6PLU and the cross section at the CR bands much larger than those at the LE bands are consistent with a sandwich structure for (C6H6)2PLU. The appearance of the two CR bands is explained on the basis of displaced sandwich structures for (C6H6)2PLU.

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Photodissociation spectroscopy of (C₆H₆)₂^PLU

Abstract

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