Photodissociation spectroscopy of (C6H6)2PLU

Kazuhiko Ohashi, Yasuhiro Nakai, Takeshi Shibata, Nobuyuki Nishi

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Abstract

The photodissociation spectrum of (C6H6)2PLU is obtained from the yields of fragment C6H6PLU ion as a function of photodissociation wavelength in the 400-1400 nm region. Two bands at 440 and 580 nm are attributed to the C ← X and the B ← X local excitation (LE) bands, respectively. Both the most intense band at 920 nm and relatively weak one at 1160 nm are assigned to charge resonance (CR) bands. The red-shift of the B ← B band from the of C6H6PLU and the cross section at the CR bands much larger than those at the LE bands are consistent with a sandwich structure for (C6H6)2PLU. The appearance of the two CR bands is explained on the basis of displaced sandwich structures for (C6H6)2PLU.

Original languageEnglish
Pages (from-to)3-14
Number of pages12
JournalLaser Chemistry
Volume14
Issue number1-3
DOIs
Publication statusPublished - 1994

All Science Journal Classification (ASJC) codes

  • Atomic and Molecular Physics, and Optics
  • Biochemistry
  • Spectroscopy

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