Photoinduced Bending Crystals of a Rhodium Dithionite Complex with n-Methoxybutyl Moieties

Yuu Kajiwara; Hikaru Yoshimizu; Kodai Matsumoto; Hidetaka Nakai

doi:10.1246/cl.210798

Photoinduced Bending Crystals of a Rhodium Dithionite Complex with n-Methoxybutyl Moieties

Yuu Kajiwara, Hikaru Yoshimizu, Kodai Matsumoto, Hidetaka Nakai

Research output: Contribution to journal › Article › peer-review

Abstract

A newly synthesized photochromic rhodium dithionite complex with n-methoxybutyl moieties has been found to provide rod-like millimeter-size crystals exhibiting photoinduced bending; the crystals show an intriguing behavior which the bending and unbending occur upon photoirradiation from the same side of the crystal. The bending mechanism was clarified by single crystal X-ray diffraction experiments.

Original language	English
Pages (from-to)	372-374
Number of pages	3
Journal	Chemistry Letters
Volume	51
Issue number	4
DOIs	https://doi.org/10.1246/cl.210798
Publication status	Published - Apr 2022
Externally published	Yes

All Science Journal Classification (ASJC) codes

Chemistry(all)

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10.1246/cl.210798

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title = "Photoinduced Bending Crystals of a Rhodium Dithionite Complex with n-Methoxybutyl Moieties",

abstract = "A newly synthesized photochromic rhodium dithionite complex with n-methoxybutyl moieties has been found to provide rod-like millimeter-size crystals exhibiting photoinduced bending; the crystals show an intriguing behavior which the bending and unbending occur upon photoirradiation from the same side of the crystal. The bending mechanism was clarified by single crystal X-ray diffraction experiments.",

author = "Yuu Kajiwara and Hikaru Yoshimizu and Kodai Matsumoto and Hidetaka Nakai",

note = "Funding Information: This work was supported by JSPS KAKENHI Grant Number JP21K05103. Publisher Copyright: {\textcopyright} 2022 The Chemical Society of Japan",

year = "2022",

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doi = "10.1246/cl.210798",

language = "English",

volume = "51",

pages = "372--374",

journal = "Chemistry Letters",

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publisher = "The Chemical Society of Japan",

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AU - Yoshimizu, Hikaru

AU - Matsumoto, Kodai

AU - Nakai, Hidetaka

PY - 2022/4

Y1 - 2022/4

N2 - A newly synthesized photochromic rhodium dithionite complex with n-methoxybutyl moieties has been found to provide rod-like millimeter-size crystals exhibiting photoinduced bending; the crystals show an intriguing behavior which the bending and unbending occur upon photoirradiation from the same side of the crystal. The bending mechanism was clarified by single crystal X-ray diffraction experiments.

AB - A newly synthesized photochromic rhodium dithionite complex with n-methoxybutyl moieties has been found to provide rod-like millimeter-size crystals exhibiting photoinduced bending; the crystals show an intriguing behavior which the bending and unbending occur upon photoirradiation from the same side of the crystal. The bending mechanism was clarified by single crystal X-ray diffraction experiments.

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Photoinduced Bending Crystals of a Rhodium Dithionite Complex with n-Methoxybutyl Moieties

Abstract

All Science Journal Classification (ASJC) codes

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