Photoinduced magnetic memory effect in an iron (II) spin-crossover complex

Hongwu Liu, Akira Fujishima, Osamu Sato

Research output: Contribution to journalArticlepeer-review

13 Citations (Scopus)

Abstract

Magnetic memory effect in an iron (II) spin-crossover induced by illumination was studied. It was found that an Fe (II) spin-cross (SC) complex could be optically changed from the low spin (LS) to the high-spin (HS) state (LIESST). It was observed that a change in the molecular structure between the seven-coordinate HS and the six-coordinate LS forms took place during the thermal spin-state transition, along with a color variation from dark blue to bluish violet. The results show that the total HS fraction on both sites is greater than 50 percent for reverse LIESST (H→S) caused by illumination with 980 nm light.

Original languageEnglish
Pages (from-to)2295-2297
Number of pages3
JournalApplied Physics Letters
Volume85
Issue number12
DOIs
Publication statusPublished - Sep 20 2004
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Physics and Astronomy (miscellaneous)

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