Photoisomerisation of the diiron carbonyl species on the acenaphthylene ligand: The first photo-directed 'switching' of the coordination site of bimetallic species on aromatic hydrocarbons

Hideo Nagashima; Takahiko Fukahori; Kenji Itoh

doi:10.1039/C39910000786

Photoisomerisation of the diiron carbonyl species on the acenaphthylene ligand: The first photo-directed 'switching' of the coordination site of bimetallic species on aromatic hydrocarbons

Hideo Nagashima, Takahiko Fukahori, Kenji Itoh

Research output: Contribution to journal › Article › peer-review

17 Citations (Scopus)

Abstract

Irradiation of (μ₂-η³: η⁵- acenaphthylene)Fe₂(CO)₅ 1 gave a novel metastable haptotropic isomer 2 (X-ray structure supported), which regenerated 1 in solution upon keeping in the dark.

Original language	English
Pages (from-to)	786-787
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	11
DOIs	https://doi.org/10.1039/C39910000786
Publication status	Published - Dec 1 1991
Externally published	Yes

All Science Journal Classification (ASJC) codes

Molecular Medicine

Access to Document

10.1039/C39910000786

Fingerprint Dive into the research topics of 'Photoisomerisation of the diiron carbonyl species on the acenaphthylene ligand: The first photo-directed 'switching' of the coordination site of bimetallic species on aromatic hydrocarbons'. Together they form a unique fingerprint.

Cite this

Photoisomerisation of the diiron carbonyl species on the acenaphthylene ligand : The first photo-directed 'switching' of the coordination site of bimetallic species on aromatic hydrocarbons. / Nagashima, Hideo; Fukahori, Takahiko; Itoh, Kenji.

In: Journal of the Chemical Society, Chemical Communications, No. 11, 01.12.1991, p. 786-787.

Research output: Contribution to journal › Article › peer-review

@article{735dc0deb61746c8ab07ae02f7491285,

title = "Photoisomerisation of the diiron carbonyl species on the acenaphthylene ligand: The first photo-directed 'switching' of the coordination site of bimetallic species on aromatic hydrocarbons",

abstract = "Irradiation of (μ2-η3: η5- acenaphthylene)Fe2(CO)5 1 gave a novel metastable haptotropic isomer 2 (X-ray structure supported), which regenerated 1 in solution upon keeping in the dark.",

author = "Hideo Nagashima and Takahiko Fukahori and Kenji Itoh",

year = "1991",

month = dec,

day = "1",

doi = "10.1039/C39910000786",

language = "English",

pages = "786--787",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "11",

}

TY - JOUR

T1 - Photoisomerisation of the diiron carbonyl species on the acenaphthylene ligand

T2 - The first photo-directed 'switching' of the coordination site of bimetallic species on aromatic hydrocarbons

AU - Nagashima, Hideo

AU - Fukahori, Takahiko

AU - Itoh, Kenji

PY - 1991/12/1

Y1 - 1991/12/1

N2 - Irradiation of (μ2-η3: η5- acenaphthylene)Fe2(CO)5 1 gave a novel metastable haptotropic isomer 2 (X-ray structure supported), which regenerated 1 in solution upon keeping in the dark.

AB - Irradiation of (μ2-η3: η5- acenaphthylene)Fe2(CO)5 1 gave a novel metastable haptotropic isomer 2 (X-ray structure supported), which regenerated 1 in solution upon keeping in the dark.

UR - http://www.scopus.com/inward/record.url?scp=37049078483&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=37049078483&partnerID=8YFLogxK

U2 - 10.1039/C39910000786

DO - 10.1039/C39910000786

M3 - Article

AN - SCOPUS:37049078483

SP - 786

EP - 787

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 11

ER -