Photoisomerisation of the diiron carbonyl species on the acenaphthylene ligand: The first photo-directed 'switching' of the coordination site of bimetallic species on aromatic hydrocarbons

Hideo Nagashima; Takahiko Fukahori; Kenji Itoh

doi:10.1039/C39910000786

Photoisomerisation of the diiron carbonyl species on the acenaphthylene ligand: The first photo-directed 'switching' of the coordination site of bimetallic species on aromatic hydrocarbons

Hideo Nagashima, Takahiko Fukahori, Kenji Itoh

Research output: Contribution to journal › Article › peer-review

18 Citations (Scopus)

Abstract

Irradiation of (μ₂-η³: η⁵- acenaphthylene)Fe₂(CO)₅ 1 gave a novel metastable haptotropic isomer 2 (X-ray structure supported), which regenerated 1 in solution upon keeping in the dark.

Original language	English
Pages (from-to)	786-787
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	11
DOIs	https://doi.org/10.1039/C39910000786
Publication status	Published - Dec 1 1991
Externally published	Yes

All Science Journal Classification (ASJC) codes

Molecular Medicine

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10.1039/C39910000786

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Photoisomerisation of the diiron carbonyl species on the acenaphthylene ligand : The first photo-directed 'switching' of the coordination site of bimetallic species on aromatic hydrocarbons. / Nagashima, Hideo; Fukahori, Takahiko; Itoh, Kenji.

In: Journal of the Chemical Society, Chemical Communications, No. 11, 01.12.1991, p. 786-787.

Research output: Contribution to journal › Article › peer-review

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abstract = "Irradiation of (μ2-η3: η5- acenaphthylene)Fe2(CO)5 1 gave a novel metastable haptotropic isomer 2 (X-ray structure supported), which regenerated 1 in solution upon keeping in the dark.",

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AU - Itoh, Kenji

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Photoisomerisation of the diiron carbonyl species on the acenaphthylene ligand: The first photo-directed 'switching' of the coordination site of bimetallic species on aromatic hydrocarbons

Abstract

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