Photoluminescent Dinuclear Lanthanide Complexes with Tris(2-pyridyl)carbinol Acting as a New Tetradentate Bridging Ligand

Masayuki Watanabe; Takuya Nankawa; Teppei Yamada; Takaumi Kimura; Kosuke Namiki; Masaki Murata; Hiroshi Nishihara; Shoichi Tachimori

doi:10.1021/ic034816n

Photoluminescent Dinuclear Lanthanide Complexes with Tris(2-pyridyl)carbinol Acting as a New Tetradentate Bridging Ligand

Masayuki Watanabe, Takuya Nankawa, Teppei Yamada, Takaumi Kimura, Kosuke Namiki, Masaki Murata, Hiroshi Nishihara, Shoichi Tachimori

Applied Chemistry

Research output: Contribution to journal › Article › peer-review

33 Citations (Scopus)

Abstract

A tripodal ligand, tris(2-pyridyl)carbinol, affords a novel tetradentate coordination mode in homodinuclear lanthanide complexes, which exhibit remarkably short distances between metal ions. The strong luminescences of Eu(III) and Tb(III) complexes with the ligand demonstrate that the ligand has a suitable excited state for energy transfer from the ligand to the Eu(III) and Tb(III) centers, respectively.

Original language	English
Pages (from-to)	6977-6979
Number of pages	3
Journal	Inorganic chemistry
Volume	42
Issue number	22
DOIs	https://doi.org/10.1021/ic034816n
Publication status	Published - Nov 3 2003

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry
Inorganic Chemistry

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10.1021/ic034816n

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abstract = "A tripodal ligand, tris(2-pyridyl)carbinol, affords a novel tetradentate coordination mode in homodinuclear lanthanide complexes, which exhibit remarkably short distances between metal ions. The strong luminescences of Eu(III) and Tb(III) complexes with the ligand demonstrate that the ligand has a suitable excited state for energy transfer from the ligand to the Eu(III) and Tb(III) centers, respectively.",

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T1 - Photoluminescent Dinuclear Lanthanide Complexes with Tris(2-pyridyl)carbinol Acting as a New Tetradentate Bridging Ligand

AU - Watanabe, Masayuki

AU - Nankawa, Takuya

AU - Yamada, Teppei

AU - Kimura, Takaumi

AU - Namiki, Kosuke

AU - Murata, Masaki

AU - Nishihara, Hiroshi

AU - Tachimori, Shoichi

PY - 2003/11/3

Y1 - 2003/11/3

N2 - A tripodal ligand, tris(2-pyridyl)carbinol, affords a novel tetradentate coordination mode in homodinuclear lanthanide complexes, which exhibit remarkably short distances between metal ions. The strong luminescences of Eu(III) and Tb(III) complexes with the ligand demonstrate that the ligand has a suitable excited state for energy transfer from the ligand to the Eu(III) and Tb(III) centers, respectively.

AB - A tripodal ligand, tris(2-pyridyl)carbinol, affords a novel tetradentate coordination mode in homodinuclear lanthanide complexes, which exhibit remarkably short distances between metal ions. The strong luminescences of Eu(III) and Tb(III) complexes with the ligand demonstrate that the ligand has a suitable excited state for energy transfer from the ligand to the Eu(III) and Tb(III) centers, respectively.

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JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 22

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Photoluminescent Dinuclear Lanthanide Complexes with Tris(2-pyridyl)carbinol Acting as a New Tetradentate Bridging Ligand

Abstract

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