Photoluminescent Dinuclear Lanthanide Complexes with Tris(2-pyridyl)carbinol Acting as a New Tetradentate Bridging Ligand

Masayuki Watanabe, Takuya Nankawa, Teppei Yamada, Takaumi Kimura, Kosuke Namiki, Masaki Murata, Hiroshi Nishihara, Shoichi Tachimori

Research output: Contribution to journalArticle

32 Citations (Scopus)

Abstract

A tripodal ligand, tris(2-pyridyl)carbinol, affords a novel tetradentate coordination mode in homodinuclear lanthanide complexes, which exhibit remarkably short distances between metal ions. The strong luminescences of Eu(III) and Tb(III) complexes with the ligand demonstrate that the ligand has a suitable excited state for energy transfer from the ligand to the Eu(III) and Tb(III) centers, respectively.

Original languageEnglish
Pages (from-to)6977-6979
Number of pages3
JournalInorganic Chemistry
Volume42
Issue number22
DOIs
Publication statusPublished - Nov 3 2003
Externally publishedYes

Fingerprint

Lanthanoid Series Elements
Methanol
Ligands
ligands
Excited states
Energy transfer
Metal ions
Luminescence
metal ions
energy transfer
luminescence
excitation

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

Cite this

Photoluminescent Dinuclear Lanthanide Complexes with Tris(2-pyridyl)carbinol Acting as a New Tetradentate Bridging Ligand. / Watanabe, Masayuki; Nankawa, Takuya; Yamada, Teppei; Kimura, Takaumi; Namiki, Kosuke; Murata, Masaki; Nishihara, Hiroshi; Tachimori, Shoichi.

In: Inorganic Chemistry, Vol. 42, No. 22, 03.11.2003, p. 6977-6979.

Research output: Contribution to journalArticle

Watanabe, M, Nankawa, T, Yamada, T, Kimura, T, Namiki, K, Murata, M, Nishihara, H & Tachimori, S 2003, 'Photoluminescent Dinuclear Lanthanide Complexes with Tris(2-pyridyl)carbinol Acting as a New Tetradentate Bridging Ligand', Inorganic Chemistry, vol. 42, no. 22, pp. 6977-6979. https://doi.org/10.1021/ic034816n
Watanabe, Masayuki ; Nankawa, Takuya ; Yamada, Teppei ; Kimura, Takaumi ; Namiki, Kosuke ; Murata, Masaki ; Nishihara, Hiroshi ; Tachimori, Shoichi. / Photoluminescent Dinuclear Lanthanide Complexes with Tris(2-pyridyl)carbinol Acting as a New Tetradentate Bridging Ligand. In: Inorganic Chemistry. 2003 ; Vol. 42, No. 22. pp. 6977-6979.
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