Photoreactive poly(vinyl alcohol) bearing p-phenylenediacrylic acid moiety

Property and photoreaction of Langmuir-Blodgett film

Fusae Nakanishi, Jun'ichi Nagasawa, Kaoru Tamada, Masaru Yoshida, Haruhisa Akiyama, Yong Kuan Gong, Koji Abe

Research output: Contribution to journalConference article

1 Citation (Scopus)

Abstract

A novel photoreactive Langmuir-Blodgett film was prepared using poly(vinyl alcohol) with conjugate diolefin moiety as the side chain. The characteristics of LB film were evaluated and its high photoreactivity as a function of molecular arrangement were investigated using spectroscopic analysis. The photoreactivity of these polymers were enhanced due to the presence of excimers. The IR spectrum of irradiated LB film showed the decrease in double bonds absorption intensity. Cycloaddition of double bonds took place in the irradiated LB film forming cyclobutane rings.

Original languageEnglish
Pages (from-to)355-356
Number of pages2
JournalAmerican Chemical Society, Polymer Preprints, Division of Polymer Chemistry
Volume39
Issue number1
Publication statusPublished - Mar 1 1998
Externally publishedYes
EventProceedings of the 1998 Dallas Meeting - Dallas, TX, USA
Duration: Mar 29 1998Apr 2 1998

Fingerprint

Bearings (structural)
Langmuir Blodgett films
Alcohols
Photoreactivity
Acids
Alkadienes
Cyclobutanes
Spectroscopic analysis
Cycloaddition
Polymers

All Science Journal Classification (ASJC) codes

  • Polymers and Plastics

Cite this

Photoreactive poly(vinyl alcohol) bearing p-phenylenediacrylic acid moiety : Property and photoreaction of Langmuir-Blodgett film. / Nakanishi, Fusae; Nagasawa, Jun'ichi; Tamada, Kaoru; Yoshida, Masaru; Akiyama, Haruhisa; Gong, Yong Kuan; Abe, Koji.

In: American Chemical Society, Polymer Preprints, Division of Polymer Chemistry, Vol. 39, No. 1, 01.03.1998, p. 355-356.

Research output: Contribution to journalConference article

Nakanishi, Fusae ; Nagasawa, Jun'ichi ; Tamada, Kaoru ; Yoshida, Masaru ; Akiyama, Haruhisa ; Gong, Yong Kuan ; Abe, Koji. / Photoreactive poly(vinyl alcohol) bearing p-phenylenediacrylic acid moiety : Property and photoreaction of Langmuir-Blodgett film. In: American Chemical Society, Polymer Preprints, Division of Polymer Chemistry. 1998 ; Vol. 39, No. 1. pp. 355-356.
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