Photostability of luminescent tris(2,4,6-trichlorophenyl)methyl radical enhanced by terminal modification of carbazole donor

Kenshiro Matsuda, Rui Xiaotian, Kazuhiro Nakamura, Minori Furukori, Takuya Hosokai, Kosuke Anraku, Kohei Nakao, Ken Albrecht

Research output: Contribution to journalArticlepeer-review

Abstract

Stable organic luminescent radicals have attracted much attention, but their stability under light irradiation is not yet satisfactory. New luminescent radicals (TTMs) based on terminal benzene ring modified carbazole donors were synthesized and evaluated. Their photostability (half-life under continuous laser irradiation) has improved by 1 order of magnitude compared to simple carbazole donors. This is a new molecular design strategy to improve the photostability of luminescent radicals without reducing other photophysical properties.

Original languageEnglish
JournalChemical Communications
DOIs
Publication statusAccepted/In press - 2022

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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