Photoswitchable dynamic magnetic relaxation in a well-isolated {Fe 2Co} double-zigzag chain

Da Peng Dong, Tao Liu, Shinji Kanegawa, Soonchul Kang, Osamu Sato, Cheng He, Chun Ying Duan

Research output: Contribution to journalArticle

88 Citations (Scopus)

Abstract

Charge-transfer-induced spin transition occurs cooperatively and reversibly in the isolated Fe III 2Co II chains of {[Fe(pzTp)(CN) 3] 2Co(4-styrylpyridine) 2} 2H 2O 2CH 3OH (1). When 1 is irradiated with 532 nm light, it shows single-chain magnetic behavior with no antiferromagnetic ordering after irradiation (see picture; C gray, N blue, B yellow; LS=low spin, HS=high spin).

Original languageEnglish
Pages (from-to)5119-5123
Number of pages5
JournalAngewandte Chemie - International Edition
Volume51
Issue number21
DOIs
Publication statusPublished - May 21 2012

Fingerprint

Magnetic relaxation
Charge transfer
Irradiation
4-stilbazole

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

Cite this

Photoswitchable dynamic magnetic relaxation in a well-isolated {Fe 2Co} double-zigzag chain. / Dong, Da Peng; Liu, Tao; Kanegawa, Shinji; Kang, Soonchul; Sato, Osamu; He, Cheng; Duan, Chun Ying.

In: Angewandte Chemie - International Edition, Vol. 51, No. 21, 21.05.2012, p. 5119-5123.

Research output: Contribution to journalArticle

Dong, Da Peng ; Liu, Tao ; Kanegawa, Shinji ; Kang, Soonchul ; Sato, Osamu ; He, Cheng ; Duan, Chun Ying. / Photoswitchable dynamic magnetic relaxation in a well-isolated {Fe 2Co} double-zigzag chain. In: Angewandte Chemie - International Edition. 2012 ; Vol. 51, No. 21. pp. 5119-5123.
@article{14c50acb517d49eeb667641c8249dcbd,
title = "Photoswitchable dynamic magnetic relaxation in a well-isolated {Fe 2Co} double-zigzag chain",
abstract = "Charge-transfer-induced spin transition occurs cooperatively and reversibly in the isolated Fe III 2Co II chains of {[Fe(pzTp)(CN) 3] 2Co(4-styrylpyridine) 2} 2H 2O 2CH 3OH (1). When 1 is irradiated with 532 nm light, it shows single-chain magnetic behavior with no antiferromagnetic ordering after irradiation (see picture; C gray, N blue, B yellow; LS=low spin, HS=high spin).",
author = "Dong, {Da Peng} and Tao Liu and Shinji Kanegawa and Soonchul Kang and Osamu Sato and Cheng He and Duan, {Chun Ying}",
year = "2012",
month = "5",
day = "21",
doi = "10.1002/anie.201105987",
language = "English",
volume = "51",
pages = "5119--5123",
journal = "Angewandte Chemie - International Edition",
issn = "1433-7851",
publisher = "John Wiley and Sons Ltd",
number = "21",

}

TY - JOUR

T1 - Photoswitchable dynamic magnetic relaxation in a well-isolated {Fe 2Co} double-zigzag chain

AU - Dong, Da Peng

AU - Liu, Tao

AU - Kanegawa, Shinji

AU - Kang, Soonchul

AU - Sato, Osamu

AU - He, Cheng

AU - Duan, Chun Ying

PY - 2012/5/21

Y1 - 2012/5/21

N2 - Charge-transfer-induced spin transition occurs cooperatively and reversibly in the isolated Fe III 2Co II chains of {[Fe(pzTp)(CN) 3] 2Co(4-styrylpyridine) 2} 2H 2O 2CH 3OH (1). When 1 is irradiated with 532 nm light, it shows single-chain magnetic behavior with no antiferromagnetic ordering after irradiation (see picture; C gray, N blue, B yellow; LS=low spin, HS=high spin).

AB - Charge-transfer-induced spin transition occurs cooperatively and reversibly in the isolated Fe III 2Co II chains of {[Fe(pzTp)(CN) 3] 2Co(4-styrylpyridine) 2} 2H 2O 2CH 3OH (1). When 1 is irradiated with 532 nm light, it shows single-chain magnetic behavior with no antiferromagnetic ordering after irradiation (see picture; C gray, N blue, B yellow; LS=low spin, HS=high spin).

UR - http://www.scopus.com/inward/record.url?scp=84862071460&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84862071460&partnerID=8YFLogxK

U2 - 10.1002/anie.201105987

DO - 10.1002/anie.201105987

M3 - Article

C2 - 22499533

AN - SCOPUS:84862071460

VL - 51

SP - 5119

EP - 5123

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

SN - 1433-7851

IS - 21

ER -