Photoswitchable dynamic magnetic relaxation in a well-isolated {Fe 2Co} double-zigzag chain

Da Peng Dong, Tao Liu, Shinji Kanegawa, Soonchul Kang, Osamu Sato, Cheng He, Chun Ying Duan

Research output: Contribution to journalArticle

94 Citations (Scopus)

Abstract

Charge-transfer-induced spin transition occurs cooperatively and reversibly in the isolated Fe III 2Co II chains of {[Fe(pzTp)(CN) 3] 2Co(4-styrylpyridine) 2} 2H 2O 2CH 3OH (1). When 1 is irradiated with 532 nm light, it shows single-chain magnetic behavior with no antiferromagnetic ordering after irradiation (see picture; C gray, N blue, B yellow; LS=low spin, HS=high spin).

Original languageEnglish
Pages (from-to)5119-5123
Number of pages5
JournalAngewandte Chemie - International Edition
Volume51
Issue number21
DOIs
Publication statusPublished - May 21 2012

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

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