Planar-chiral [7]orthocyclophanes

Katsuhiko Tomooka, Chisato Iso, Kazuhiro Uehara, Masaki Suzuki, Rie Nishikawa-Shimono, Kazunobu Igawa

Research output: Contribution to journalArticle

14 Citations (Scopus)

Abstract

Just plain chiral: The [7]orthocyclophanes 1, having an E-olefinic ansa chain, exhibit planar chirality at ambient temperature and their stereochemical stabilities are highly dependent upon the embedded X group in the ansa chain. Inter- and intramolecular transformations of 1 (where X=NTs) provide a variety of nitrogen-containing chiral molecules in a stereospecific manner. Ts=4-toluenesulfonyl.

Original languageEnglish
Pages (from-to)10355-10358
Number of pages4
JournalAngewandte Chemie - International Edition
Volume51
Issue number41
DOIs
Publication statusPublished - Oct 8 2012

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

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