TY - JOUR
T1 - Planar chiral dialkoxysilane
T2 - Introduction of inherent chirality and high reactivity in conventional achiral alkene
AU - Tomooka, Katsuhiko
AU - Miyasaka, Shouji
AU - Motomura, Shougo
AU - Igawa, Kazunobu
PY - 2014/6/16
Y1 - 2014/6/16
N2 - A simple eight-membered dialkoxysilane (E)-1 prepared from 2-pentene-1,5-diol, showed remarkably stable planar chirality along with high reactivity toward epoxidation, Diels-Alder reaction, and cycloaddition reaction with azide. Enriching alkenes: A simple eight-membered dialkoxysilane, prepared from 2-pentene-1,5-diol, shows remarkably stable planar chirality along with quite a high reactivity in epoxidation reactions, Diels-Alder reactions, and in cycloaddition reactions with azide (see scheme).
AB - A simple eight-membered dialkoxysilane (E)-1 prepared from 2-pentene-1,5-diol, showed remarkably stable planar chirality along with high reactivity toward epoxidation, Diels-Alder reaction, and cycloaddition reaction with azide. Enriching alkenes: A simple eight-membered dialkoxysilane, prepared from 2-pentene-1,5-diol, shows remarkably stable planar chirality along with quite a high reactivity in epoxidation reactions, Diels-Alder reactions, and in cycloaddition reactions with azide (see scheme).
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U2 - 10.1002/chem.201402434
DO - 10.1002/chem.201402434
M3 - Article
AN - SCOPUS:84902492633
VL - 20
SP - 7598
EP - 7602
JO - Chemistry - A European Journal
JF - Chemistry - A European Journal
SN - 0947-6539
IS - 25
ER -