Planar chiral dialkoxysilane: Introduction of inherent chirality and high reactivity in conventional achiral alkene

Katsuhiko Tomooka, Shouji Miyasaka, Shougo Motomura, Kazunobu Igawa

Research output: Contribution to journalArticlepeer-review

10 Citations (Scopus)

Abstract

A simple eight-membered dialkoxysilane (E)-1 prepared from 2-pentene-1,5-diol, showed remarkably stable planar chirality along with high reactivity toward epoxidation, Diels-Alder reaction, and cycloaddition reaction with azide. Enriching alkenes: A simple eight-membered dialkoxysilane, prepared from 2-pentene-1,5-diol, shows remarkably stable planar chirality along with quite a high reactivity in epoxidation reactions, Diels-Alder reactions, and in cycloaddition reactions with azide (see scheme).

Original languageEnglish
Pages (from-to)7598-7602
Number of pages5
JournalChemistry - A European Journal
Volume20
Issue number25
DOIs
Publication statusPublished - Jun 16 2014

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Organic Chemistry

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