Abstract
A simple eight-membered dialkoxysilane (E)-1 prepared from 2-pentene-1,5-diol, showed remarkably stable planar chirality along with high reactivity toward epoxidation, Diels-Alder reaction, and cycloaddition reaction with azide. Enriching alkenes: A simple eight-membered dialkoxysilane, prepared from 2-pentene-1,5-diol, shows remarkably stable planar chirality along with quite a high reactivity in epoxidation reactions, Diels-Alder reactions, and in cycloaddition reactions with azide (see scheme).
| Original language | English |
|---|---|
| Pages (from-to) | 7598-7602 |
| Number of pages | 5 |
| Journal | Chemistry - A European Journal |
| Volume | 20 |
| Issue number | 25 |
| DOIs | |
| Publication status | Published - Jun 16 2014 |
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All Science Journal Classification (ASJC) codes
- Catalysis
- Organic Chemistry
Cite this
Planar chiral dialkoxysilane : Introduction of inherent chirality and high reactivity in conventional achiral alkene. / Tomooka, Katsuhiko; Miyasaka, Shouji; Motomura, Shougo; Igawa, Kazunobu.
In: Chemistry - A European Journal, Vol. 20, No. 25, 16.06.2014, p. 7598-7602.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Planar chiral dialkoxysilane
T2 - Introduction of inherent chirality and high reactivity in conventional achiral alkene
AU - Tomooka, Katsuhiko
AU - Miyasaka, Shouji
AU - Motomura, Shougo
AU - Igawa, Kazunobu
PY - 2014/6/16
Y1 - 2014/6/16
N2 - A simple eight-membered dialkoxysilane (E)-1 prepared from 2-pentene-1,5-diol, showed remarkably stable planar chirality along with high reactivity toward epoxidation, Diels-Alder reaction, and cycloaddition reaction with azide. Enriching alkenes: A simple eight-membered dialkoxysilane, prepared from 2-pentene-1,5-diol, shows remarkably stable planar chirality along with quite a high reactivity in epoxidation reactions, Diels-Alder reactions, and in cycloaddition reactions with azide (see scheme).
AB - A simple eight-membered dialkoxysilane (E)-1 prepared from 2-pentene-1,5-diol, showed remarkably stable planar chirality along with high reactivity toward epoxidation, Diels-Alder reaction, and cycloaddition reaction with azide. Enriching alkenes: A simple eight-membered dialkoxysilane, prepared from 2-pentene-1,5-diol, shows remarkably stable planar chirality along with quite a high reactivity in epoxidation reactions, Diels-Alder reactions, and in cycloaddition reactions with azide (see scheme).
UR - http://www.scopus.com/inward/record.url?scp=84902492633&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84902492633&partnerID=8YFLogxK
U2 - 10.1002/chem.201402434
DO - 10.1002/chem.201402434
M3 - Article
AN - SCOPUS:84902492633
VL - 20
SP - 7598
EP - 7602
JO - Chemistry - A European Journal
JF - Chemistry - A European Journal
SN - 0947-6539
IS - 25
ER -