Platinum complex catalyzed reaction of tributyltin cyanide with alkynes

Yasushi Obora, Angelo S. Baleta, Makoto Tokunaga, Yasushi Tsuji

Research output: Contribution to journalArticlepeer-review

46 Citations (Scopus)

Abstract

In the presence of a catalytic amount (5 mol%) of a platinum complex, tributyltin cyanide (1) reacts with dimethyl- (2a) or diethyl acetylenedicarboxylate (2b) to afford cyanostannylation adducts (3a, b) in excellent yields. The reaction proceeds highly selectively affording only a (Z)-isomer. The compounds 3a, b are novel products which possess synthetically useful cyano, alkenylstannyl and alkoxycarbonyl functionalities in the same molecule. Two alkoxycarbonyl functionalities may be indispensable on each alkyne carbon to accomplish the cyanostannylation reaction. Reaction with terminal alkynes gave the stannylated product (6).

Original languageEnglish
Pages (from-to)173-177
Number of pages5
JournalJournal of Organometallic Chemistry
Volume660
Issue number2
DOIs
Publication statusPublished - Oct 22 2002
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

Fingerprint Dive into the research topics of 'Platinum complex catalyzed reaction of tributyltin cyanide with alkynes'. Together they form a unique fingerprint.

Cite this