Polymer hybridization by macromolecular olefin cross metathesis reaction -I

Takatoshi Muta, Hideyuki Otsuka, Atsushi Takahara

Research output: Contribution to conferencePaper

Abstract

The olefin cross metathesis reaction comes down to an apparent interchange of carbon atoms between two double bonds. The metathesis reaction was carried out in dichloromethane using the mixture of frationated polyester containing C=C double bonds in its backbone structure and 1,4-polybutadiene in the presence of Grubbs catalyst. DSC analyses of the polymer obtained in the reaction was carried out. In the case of polyester/polybutadiene blend, melting endothermic peak and glass transition temperatures derived from polyester and polybutadiene were observed. On the other hand, the lowering of melting point was confirmed in hybrid polymer after macromolecular metathesis reaction. This result indicates that the length of the main chain of polyester is shorter than that of original polyester, and the lamellar thickness of the polyester crystal decreased in the hybrid polymer.

Original languageEnglish
Number of pages1
Publication statusPublished - Dec 1 2005
Event54th SPSJ Annual Meeting 2005 - Yokohama, Japan
Duration: May 25 2005May 27 2005

Other

Other54th SPSJ Annual Meeting 2005
CountryJapan
CityYokohama
Period5/25/055/27/05

Fingerprint

Olefins
Polyesters
Polybutadienes
Polymers
Dichloromethane
Interchanges
Melting point
Melting
Atoms
Crystals
Catalysts
Carbon

All Science Journal Classification (ASJC) codes

  • Engineering(all)

Cite this

Muta, T., Otsuka, H., & Takahara, A. (2005). Polymer hybridization by macromolecular olefin cross metathesis reaction -I. Paper presented at 54th SPSJ Annual Meeting 2005, Yokohama, Japan.

Polymer hybridization by macromolecular olefin cross metathesis reaction -I. / Muta, Takatoshi; Otsuka, Hideyuki; Takahara, Atsushi.

2005. Paper presented at 54th SPSJ Annual Meeting 2005, Yokohama, Japan.

Research output: Contribution to conferencePaper

Muta, T, Otsuka, H & Takahara, A 2005, 'Polymer hybridization by macromolecular olefin cross metathesis reaction -I', Paper presented at 54th SPSJ Annual Meeting 2005, Yokohama, Japan, 5/25/05 - 5/27/05.
Muta T, Otsuka H, Takahara A. Polymer hybridization by macromolecular olefin cross metathesis reaction -I. 2005. Paper presented at 54th SPSJ Annual Meeting 2005, Yokohama, Japan.
Muta, Takatoshi ; Otsuka, Hideyuki ; Takahara, Atsushi. / Polymer hybridization by macromolecular olefin cross metathesis reaction -I. Paper presented at 54th SPSJ Annual Meeting 2005, Yokohama, Japan.1 p.
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