Polymer scrambling: Macromolecular radical crossover reaction between the main chains of alkoxyamine-based dynamic covalent polymers

Hideyuki Otsuka; Koichiro Aotani; Yuji Higaki; Atsushi Takahara

doi:10.1021/ja0340477

Polymer scrambling: Macromolecular radical crossover reaction between the main chains of alkoxyamine-based dynamic covalent polymers

Hideyuki Otsuka, Koichiro Aotani, Yuji Higaki, Atsushi Takahara

Department of Applied Molecular Chemistry

Research output: Contribution to journal › Article › peer-review

74 Citations (Scopus)

Abstract

A novel polymer hybridization method, "polymer scrambling", was developed on the basis of the macromolecular radical crossover reaction between the main chains of dynamic covalent polymers. The macromolecular crossover reaction was successfully monitored by GPC and NMR measurements. The present methodology is innovative for the preparation of novel polymer hybrid materials at the nanometer scale.

Original language	English
Pages (from-to)	4064-4065
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	125
Issue number	14
DOIs	https://doi.org/10.1021/ja0340477
Publication status	Published - Apr 9 2003

All Science Journal Classification (ASJC) codes

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja0340477

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abstract = "A novel polymer hybridization method, {"}polymer scrambling{"}, was developed on the basis of the macromolecular radical crossover reaction between the main chains of dynamic covalent polymers. The macromolecular crossover reaction was successfully monitored by GPC and NMR measurements. The present methodology is innovative for the preparation of novel polymer hybrid materials at the nanometer scale.",

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AU - Higaki, Yuji

AU - Takahara, Atsushi

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AB - A novel polymer hybridization method, "polymer scrambling", was developed on the basis of the macromolecular radical crossover reaction between the main chains of dynamic covalent polymers. The macromolecular crossover reaction was successfully monitored by GPC and NMR measurements. The present methodology is innovative for the preparation of novel polymer hybrid materials at the nanometer scale.

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Polymer scrambling: Macromolecular radical crossover reaction between the main chains of alkoxyamine-based dynamic covalent polymers

Abstract

All Science Journal Classification (ASJC) codes

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