TY - JOUR
T1 - Polymerization of allyl compound bearing perfluoroisopropenyl group
AU - Narita, Tadashi
AU - Fujiwara, Hirotada
AU - Hamana, Hiroshi
N1 - Funding Information:
The authors thank Mr. T. Sekiguchi for his experimental assistance. This work was financially supported in part by the “High-Tech Research Center” Project of Saitama Institute of Technology: matching fund subsidy from the Ministry of Education, Culture, Sports, Science and Technology of Japan, 1999–2008, to which the authors are grateful.
PY - 2007/11
Y1 - 2007/11
N2 - The investigation on the radical polymerization reactivity of 4-pentenoyloxypentafluoropropene [CH2{double bond, long}CH-CH2CH2-COOC(CF3){double bond, long}CF2] (PPF) was carried out since cyclopolymerization of perfluoroisopropenyl vinylacetate [CH2{double bond, long}CH-CH2-COOC(CF3){double bond, long}CF2] takes place under radical polymerization condition to produce the polymer possessing 5-membered-ring structure in main chain. The soluble polymer of PPF yielded by allyl polymerization bearing 1.8 × 104(over(DP, -) = 78) as the highest molecular weight initiated with di-tert-butyl peroxide was produced instead of cyclized polymer bearing 6-membered-ring structure. The polymer possesses perfluoroisopropenyl groups in side chains.
AB - The investigation on the radical polymerization reactivity of 4-pentenoyloxypentafluoropropene [CH2{double bond, long}CH-CH2CH2-COOC(CF3){double bond, long}CF2] (PPF) was carried out since cyclopolymerization of perfluoroisopropenyl vinylacetate [CH2{double bond, long}CH-CH2-COOC(CF3){double bond, long}CF2] takes place under radical polymerization condition to produce the polymer possessing 5-membered-ring structure in main chain. The soluble polymer of PPF yielded by allyl polymerization bearing 1.8 × 104(over(DP, -) = 78) as the highest molecular weight initiated with di-tert-butyl peroxide was produced instead of cyclized polymer bearing 6-membered-ring structure. The polymer possesses perfluoroisopropenyl groups in side chains.
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U2 - 10.1016/j.reactfunctpolym.2007.06.010
DO - 10.1016/j.reactfunctpolym.2007.06.010
M3 - Article
AN - SCOPUS:35248887150
SN - 1381-5148
VL - 67
SP - 1181
EP - 1186
JO - Reactive and Functional Polymers
JF - Reactive and Functional Polymers
IS - 11 SPEC. ISS.
ER -