Polymerization of allyl compound bearing perfluoroisopropenyl group

Tadashi Narita, Hirotada Fujiwara, Hiroshi Hamana

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

The investigation on the radical polymerization reactivity of 4-pentenoyloxypentafluoropropene [CH2{double bond, long}CH-CH2CH2-COOC(CF3){double bond, long}CF2] (PPF) was carried out since cyclopolymerization of perfluoroisopropenyl vinylacetate [CH2{double bond, long}CH-CH2-COOC(CF3){double bond, long}CF2] takes place under radical polymerization condition to produce the polymer possessing 5-membered-ring structure in main chain. The soluble polymer of PPF yielded by allyl polymerization bearing 1.8 × 104(over(DP, -) = 78) as the highest molecular weight initiated with di-tert-butyl peroxide was produced instead of cyclized polymer bearing 6-membered-ring structure. The polymer possesses perfluoroisopropenyl groups in side chains.

Original languageEnglish
Pages (from-to)1181-1186
Number of pages6
JournalReactive and Functional Polymers
Volume67
Issue number11 SPEC. ISS.
DOIs
Publication statusPublished - Nov 2007
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Environmental Chemistry
  • Biochemistry
  • Chemical Engineering(all)
  • Polymers and Plastics
  • Materials Chemistry

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