Polymerization of allyl compound bearing perfluoroisopropenyl group

Tadashi Narita, Hirotada Fujiwara, Hiroshi Hamana

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

The investigation on the radical polymerization reactivity of 4-pentenoyloxypentafluoropropene [CH2{double bond, long}CH-CH2CH2-COOC(CF3){double bond, long}CF2] (PPF) was carried out since cyclopolymerization of perfluoroisopropenyl vinylacetate [CH2{double bond, long}CH-CH2-COOC(CF3){double bond, long}CF2] takes place under radical polymerization condition to produce the polymer possessing 5-membered-ring structure in main chain. The soluble polymer of PPF yielded by allyl polymerization bearing 1.8 × 104(over(DP, -) = 78) as the highest molecular weight initiated with di-tert-butyl peroxide was produced instead of cyclized polymer bearing 6-membered-ring structure. The polymer possesses perfluoroisopropenyl groups in side chains.

Original languageEnglish
Pages (from-to)1181-1186
Number of pages6
JournalReactive and Functional Polymers
Volume67
Issue number11 SPEC. ISS.
DOIs
Publication statusPublished - Jan 1 2007
Externally publishedYes

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Allyl Compounds
Bearings (structural)
polymerization
Polymerization
Polymers
polymer
Free radical polymerization
Peroxides
Molecular Weight
Molecular weight

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Environmental Chemistry
  • Biochemistry
  • Chemical Engineering(all)
  • Polymers and Plastics
  • Materials Chemistry

Cite this

Polymerization of allyl compound bearing perfluoroisopropenyl group. / Narita, Tadashi; Fujiwara, Hirotada; Hamana, Hiroshi.

In: Reactive and Functional Polymers, Vol. 67, No. 11 SPEC. ISS., 01.01.2007, p. 1181-1186.

Research output: Contribution to journalArticle

Narita, Tadashi ; Fujiwara, Hirotada ; Hamana, Hiroshi. / Polymerization of allyl compound bearing perfluoroisopropenyl group. In: Reactive and Functional Polymers. 2007 ; Vol. 67, No. 11 SPEC. ISS. pp. 1181-1186.
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