POLYMERIZATION OF VINYL COMPOUNDS WITH HETEROCYCLIC GROUPS-4

C ASO C, T KUNITAKE T, M SHINSENJI M, H MIYAZAKI H

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Abstract

2-Vinylthiophene was found to undergo thermal polymerization; with benzene as diluent, overall rate of polymerization was proportional to 2. 5 power of monomer concentration, suggesting that thermal initiation is termolecular process; following Arrhenius equation was obtained from polymerization data for range 55 to 100 C; activation energy of thermal initiation was estimated to be 28. 2 kcal/mole, which was similar to those values obtained for styrene and 2-vinylfuran.

Original languageEnglish
Pages (from-to)1497-1508
Number of pages12
JournalJ Polymer Science-Polymer Chem
Volume7
Issue number6 Pt A-1
Publication statusPublished - Jan 1 1969
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Engineering(all)

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  • Cite this

    ASO C, C., KUNITAKE T, T., SHINSENJI M, M., & MIYAZAKI H, H. (1969). POLYMERIZATION OF VINYL COMPOUNDS WITH HETEROCYCLIC GROUPS-4. J Polymer Science-Polymer Chem, 7(6 Pt A-1), 1497-1508.