Porous interpenetrating metal-organic frameworks with hierarchical nodes

Teppei Yamada, Shoji Iwakiri, Takafumi Hara, Katsuhiko Kanaizuka, Mohamedally Kurmoo, Hiroshi Kitagawa

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35 Citations (Scopus)

Abstract

We present the solvothermal syntheses, X-ray crystal structures, and gas sorption properties of a series of zinc-dicarboxylate-polypyridine where the dicarboxylate is 1,4-benzenedicarboxylate, 4,4′-biphenyldicarboxylate, or sulfone-4,4′-biphenyldicarboxylate and the polypyridine is bipyridine or 1,4-bis(4-pyridylethynyl)benzene. The structures consist of hierarchical two-, three-, and four-blade dimer or trimer nodes which generate the square or triangular topologies of the metal-carboxylate layers which are pillared by the bipyridine. Two-and 3-fold interpenetration of frameworks was observed depending on the length of both the carboxylate and the bipyridine. In all cases, the structure sustains a variable degree of space within the metal-organic frameworks where solvents are located. The solvents are easily lost and the structures display accessible voids where adsorption of other gases can be realized. The present set of compounds reveals a picture that does not conform to the current belief that interpenetration of lattices results in highly compact structures.

Original languageEnglish
Pages (from-to)1798-1806
Number of pages9
JournalCrystal Growth and Design
Volume11
Issue number5
DOIs
Publication statusPublished - May 4 2011

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All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

Yamada, T., Iwakiri, S., Hara, T., Kanaizuka, K., Kurmoo, M., & Kitagawa, H. (2011). Porous interpenetrating metal-organic frameworks with hierarchical nodes. Crystal Growth and Design, 11(5), 1798-1806. https://doi.org/10.1021/cg1017278