Positive charge distribution in (benzene)1(toleune)2 + and (benzene)2(toluene)1 + studied by photodissociation spectroscopy

Yoshiya Inokuchi, Kazuhiko Ohashi, Hiroshi Sekiya, Nobuyuki Nishi

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

The electronic and vibrational spectra of the benzene-toluene heterotrimer ions, B1T2 + and B2T1 +, were observed using the tunable near-infrared and infrared lasers and the tandem mass spectrometer. The electronic spectra of both ions display the CR band, demonstrating that the positive charge is not localized on one molecule. The results were explained by the CR interaction between B2 and T.

Original languageEnglish
Pages (from-to)10648-10653
Number of pages6
JournalJournal of Chemical Physics
Volume117
Issue number23
DOIs
Publication statusPublished - Dec 15 2002

All Science Journal Classification (ASJC) codes

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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