Post-synthetic Modification of a Dinuclear Spin Crossover Iron(III) Complex

Yuki Komatsumaru, Manabu Nakaya, Fumiya Kobayashi, Ryo Ohtani, Masaaki Nakamura, Leonard F. Lindoy, Shinya Hayami

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

The dinuclear iron(III) complex [Fe(salten)2(bipytz)](BPh4)2·EtOH (1) was synthesized and its post-synthesis modification yielded [Fe(salten)2(bipydz)](BPh4)2·EtOH (2). The crystal structures and magnetic behaviors of 1 and 2 were investigated by variable temperature XRD, magnetic susceptibility, and Mössbauer spectra measurements, with each of these dinuclear iron(III) complexes exhibiting gradual spin crossover behavior.

Original languageEnglish
Pages (from-to)729-734
Number of pages6
JournalZeitschrift fur Anorganische und Allgemeine Chemie
Volume644
Issue number14
DOIs
Publication statusPublished - Aug 2 2018
Externally publishedYes

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Iron
Magnetic susceptibility
Crystal structure
Temperature

All Science Journal Classification (ASJC) codes

  • Inorganic Chemistry

Cite this

Post-synthetic Modification of a Dinuclear Spin Crossover Iron(III) Complex. / Komatsumaru, Yuki; Nakaya, Manabu; Kobayashi, Fumiya; Ohtani, Ryo; Nakamura, Masaaki; Lindoy, Leonard F.; Hayami, Shinya.

In: Zeitschrift fur Anorganische und Allgemeine Chemie, Vol. 644, No. 14, 02.08.2018, p. 729-734.

Research output: Contribution to journalArticle

Komatsumaru, Y, Nakaya, M, Kobayashi, F, Ohtani, R, Nakamura, M, Lindoy, LF & Hayami, S 2018, 'Post-synthetic Modification of a Dinuclear Spin Crossover Iron(III) Complex', Zeitschrift fur Anorganische und Allgemeine Chemie, vol. 644, no. 14, pp. 729-734. https://doi.org/10.1002/zaac.201800087
Komatsumaru, Yuki ; Nakaya, Manabu ; Kobayashi, Fumiya ; Ohtani, Ryo ; Nakamura, Masaaki ; Lindoy, Leonard F. ; Hayami, Shinya. / Post-synthetic Modification of a Dinuclear Spin Crossover Iron(III) Complex. In: Zeitschrift fur Anorganische und Allgemeine Chemie. 2018 ; Vol. 644, No. 14. pp. 729-734.
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