The dinuclear iron(III) complex [Fe(salten)2(bipytz)](BPh4)2·EtOH (1) was synthesized and its post-synthesis modification yielded [Fe(salten)2(bipydz)](BPh4)2·EtOH (2). The crystal structures and magnetic behaviors of 1 and 2 were investigated by variable temperature XRD, magnetic susceptibility, and Mössbauer spectra measurements, with each of these dinuclear iron(III) complexes exhibiting gradual spin crossover behavior.
|Number of pages||6|
|Journal||Zeitschrift fur Anorganische und Allgemeine Chemie|
|Publication status||Published - Aug 2 2018|
All Science Journal Classification (ASJC) codes
- Inorganic Chemistry