Post-synthetic Modification of a Dinuclear Spin Crossover Iron(III) Complex

Yuki Komatsumaru, Manabu Nakaya, Fumiya Kobayashi, Ryo Ohtani, Masaaki Nakamura, Leonard F. Lindoy, Shinya Hayami

Research output: Contribution to journalArticlepeer-review

4 Citations (Scopus)

Abstract

The dinuclear iron(III) complex [Fe(salten)2(bipytz)](BPh4)2·EtOH (1) was synthesized and its post-synthesis modification yielded [Fe(salten)2(bipydz)](BPh4)2·EtOH (2). The crystal structures and magnetic behaviors of 1 and 2 were investigated by variable temperature XRD, magnetic susceptibility, and Mössbauer spectra measurements, with each of these dinuclear iron(III) complexes exhibiting gradual spin crossover behavior.

Original languageEnglish
Pages (from-to)729-734
Number of pages6
JournalZeitschrift fur Anorganische und Allgemeine Chemie
Volume644
Issue number14
DOIs
Publication statusPublished - Aug 2 2018
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Inorganic Chemistry

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