Potentiometric oxygen sensor operable in low temperature by applying LaGaO3-based oxide for electrolyte

Tatsumi Ishihara, Masakazu Higuchi, Haruyoshi Furutani, Tomokatsu Fukushima, Hiroyasu Nishiguchi, Yusaku Takita

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18 Citations (Scopus)

Abstract

A perovskite-type oxide of LaGaO3 doped with Sr and Mg exhibits a high oxide ion conductivity over a wide range of oxygen partial pressures. In this study, the application of LaGaO3-based oxide as the electrolyte of a potentiometric oxygen sensor was investigated. It became clear that silver is the most effective electrode for decreasing the operating temperature. Although a temperature higher than 800 K is required when a conventional Y2O3-stabilized ZrO2 electrolyte is used, an operating temperature as low as 600 K is adequate when La1-xSrxGa0.8Mg0.2O3 at X = 0.1 and 0.2 is used. The open-circuit potential was slightly smaller than that estimated with the Nernst equation. There was agreement with the Nernst equation down to 673 K when Nd-doped LaGaO3-based oxide was used. Moreover, 90% of the response was attained within 15 s at 673 K for the sensor with Nd-doped LaGaO3-based oxide.

Original languageEnglish
JournalJournal of the Electrochemical Society
Volume144
Issue number5
DOIs
Publication statusPublished - Jan 1 1997
Externally publishedYes

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All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Renewable Energy, Sustainability and the Environment
  • Condensed Matter Physics
  • Surfaces, Coatings and Films
  • Electrochemistry
  • Materials Chemistry

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