(PPh3)3RhCI-Catalyzed Hydrosilylation of Unsaturated Molecules by 1,2-Bls(dimethylsilyl)ethane

Unprecedented Rate Difference between Two Sl-H Bonds

Hideo Nagashima, Kazuo Tatebe, Toshinori Ishibashi, Jun Sakaklbara, Kenji Itoh

Research output: Contribution to journalArticle

34 Citations (Scopus)

Abstract

(PPh3)3RhCI catalyzed rapid hydrosilylation of ketones, olefins, and acetylenes with 1,2-bis(dimethylsilyl)ethane (1) to form monohydrosilylation products Me2HSi(CH2)2SiMe2Z (Z = alkoxy, alkyl, vinyl), selectively.

Original languageEnglish
Pages (from-to)2495-2496
Number of pages2
JournalOrganometallics
Volume8
Issue number10
DOIs
Publication statusPublished - Oct 1 1989
Externally publishedYes

Fingerprint

Hydrosilylation
Ethane
Alkynes
Alkenes
Ketones
ketones
acetylene
ethane
alkenes
Molecules
products
molecules
alkoxyl radical

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

Cite this

(PPh3)3RhCI-Catalyzed Hydrosilylation of Unsaturated Molecules by 1,2-Bls(dimethylsilyl)ethane : Unprecedented Rate Difference between Two Sl-H Bonds. / Nagashima, Hideo; Tatebe, Kazuo; Ishibashi, Toshinori; Sakaklbara, Jun; Itoh, Kenji.

In: Organometallics, Vol. 8, No. 10, 01.10.1989, p. 2495-2496.

Research output: Contribution to journalArticle

Nagashima, Hideo ; Tatebe, Kazuo ; Ishibashi, Toshinori ; Sakaklbara, Jun ; Itoh, Kenji. / (PPh3)3RhCI-Catalyzed Hydrosilylation of Unsaturated Molecules by 1,2-Bls(dimethylsilyl)ethane : Unprecedented Rate Difference between Two Sl-H Bonds. In: Organometallics. 1989 ; Vol. 8, No. 10. pp. 2495-2496.
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