Ppm level methane detection using micro-thermoelectric gas sensors with Pd/Al2O3 combustion catalyst films

Daisuke Nagai, Maiko Nishibori, Toshio Itoh, Tsutomu Kawabe, Kazuo Sato, Woosuck Shin

Research output: Contribution to journalArticle

33 Citations (Scopus)

Abstract

The CH4 combustion performance of a micro-thermoelectric gas sensor (TGS) with Pd-Al2O3 catalysts prepared using two different methods, impregnation and colloid mixing, has been investigated. Three crystal phases of Al2O3, α, θ, and γ, were used for the catalyst support; the Pd/θ-Al2O3 catalyst showed the best combustion performance. The Pd/θ-Al2O3 catalyst exhibited the best dispersion of Pd nanoparticles as analyzed by both a pulse adsorption technique and transmission electron microscopy. The effect of the catalyst thickness on the H2 and CH4 detection performance of the TGS using this Pd/θ-Al2O3 catalyst prepared using a colloid mixing method was investigated. It was found that the response voltage, ΔV, of the TGS to CH4 increased with increasing film thickness, but the ΔV to H2 decreased. The TGS with the Pd/θ-Al2O3 catalyst whose thickness was 35 μm could detect as low as 1 ppm of CH4 in air by the thermoelectric conversion of the combustor heat to an electrical voltage.

Original languageEnglish
Pages (from-to)488-494
Number of pages7
JournalSensors and Actuators, B: Chemical
Volume206
DOIs
Publication statusPublished - Jan 2015

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Instrumentation
  • Condensed Matter Physics
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Electrical and Electronic Engineering
  • Materials Chemistry

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