Precise synthesis and characterization of catenated copolymer

Yutaka Ohta, Yuuki Kushida, Daisuke Kawaguchi, Atsushi Takano, Yushu Matsushita

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

Morphology of 2-component catenated copolymer is quite interesting, because it is expected that the catenated copolymer forms peculiar microphase-separated structure and interfacial structure comparing with regular block copolymers. The catenated copolymer consisting of poly(styrene-b-2-isopropenylnaphthalene) (polymer A) and polyisoprene (polymer B) was prepared using anionic polymerization as follows; (1) telechelic polymer A and B were prepared, (2) the telechelic A was cyclized by end-to-end closure to prepare cyclic polymer, (3) the cyclic polymer A was radical-anionized by the reaction with potassium in THF, and (4) telechelic polymer B was cyclized with radical-anionized ring polymer A in dilute condition. Formation of catenated polymer was confirmed by GPC by use of preferential detection of naphthalene by UV detector (λ=320nm).

Original languageEnglish
Title of host publicationPolymer Preprints, Japan - 55th SPSJ Annual Meeting
Pages410
Number of pages1
Volume55
Edition1
Publication statusPublished - 2006
Externally publishedYes
Event55th SPSJ Annual Meeting - Nagoya, Japan
Duration: May 24 2006May 26 2006

Other

Other55th SPSJ Annual Meeting
CountryJapan
CityNagoya
Period5/24/065/26/06

All Science Journal Classification (ASJC) codes

  • Engineering(all)

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  • Cite this

    Ohta, Y., Kushida, Y., Kawaguchi, D., Takano, A., & Matsushita, Y. (2006). Precise synthesis and characterization of catenated copolymer. In Polymer Preprints, Japan - 55th SPSJ Annual Meeting (1 ed., Vol. 55, pp. 410)