Preparation and characterization of Pd loaded Sr-deficient K2NiF4-type (La, Sr)2MnO4 catalysts for NO-CO reaction

Tomoki Uchiyama, Reiko Karita, Maiko Nishibori, Hisahiro Einaga, Yasutake Teraoka

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Abstract

Pd-loaded K2NiF4-type perovskite oxides, Pd/La0.2Sr1.8-xMnO4 were prepared by liquid-phase adsorption process, and their structural and catalytic properties were investigated. Pd deposition was carried out by mixing La0.2Sr1.8MnO4 with Pd(NO3)2 in aqueous solution, followed by filtration, drying, and calcination at 800 °C. During the Pd deposition process, 5% of Sr in La0.2Sr1.8MnO4 oxides was dissolved into the aqueous phase, whereas the perovskite structure retained. The content of Pd loaded on La0.2Sr1.8MnO4 was 0.24 wt%. X-ray absorption spectroscopy studies showed that highly dispersed PdO nanoparticles were supported on Pd/La0.2Sr1.8MnO4 prepared by the liquid-phase adsorption process, whereas aggregated PdO particles were formed on Pd/La0.2Sr1.8MnO4 prepared by an impregnation method. The Pd/La0.2Sr1.8MnO4 catalyst prepared by the liquid-phase adsorption process exhibited higher catalytic activity for NO-CO reaction than the 0.24 wt% Pd/La0.2Sr1.8MnO4 catalyst prepared by the impregnation method.

Original languageEnglish
Pages (from-to)7-13
Number of pages7
JournalCatalysis Today
Volume251
DOIs
Publication statusPublished - Aug 1 2015

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Carbon Monoxide
Adsorption
Impregnation
Perovskite
Oxides
Catalysts
Liquids
X ray absorption spectroscopy
Calcination
Catalyst activity
Drying
Nanoparticles
perovskite

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

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Preparation and characterization of Pd loaded Sr-deficient K2NiF4-type (La, Sr)2MnO4 catalysts for NO-CO reaction. / Uchiyama, Tomoki; Karita, Reiko; Nishibori, Maiko; Einaga, Hisahiro; Teraoka, Yasutake.

In: Catalysis Today, Vol. 251, 01.08.2015, p. 7-13.

Research output: Contribution to journalArticle

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abstract = "Pd-loaded K2NiF4-type perovskite oxides, Pd/La0.2Sr1.8-xMnO4 were prepared by liquid-phase adsorption process, and their structural and catalytic properties were investigated. Pd deposition was carried out by mixing La0.2Sr1.8MnO4 with Pd(NO3)2 in aqueous solution, followed by filtration, drying, and calcination at 800 °C. During the Pd deposition process, 5{\%} of Sr in La0.2Sr1.8MnO4 oxides was dissolved into the aqueous phase, whereas the perovskite structure retained. The content of Pd loaded on La0.2Sr1.8MnO4 was 0.24 wt{\%}. X-ray absorption spectroscopy studies showed that highly dispersed PdO nanoparticles were supported on Pd/La0.2Sr1.8MnO4 prepared by the liquid-phase adsorption process, whereas aggregated PdO particles were formed on Pd/La0.2Sr1.8MnO4 prepared by an impregnation method. The Pd/La0.2Sr1.8MnO4 catalyst prepared by the liquid-phase adsorption process exhibited higher catalytic activity for NO-CO reaction than the 0.24 wt{\%} Pd/La0.2Sr1.8MnO4 catalyst prepared by the impregnation method.",
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AU - Einaga, Hisahiro

AU - Teraoka, Yasutake

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AB - Pd-loaded K2NiF4-type perovskite oxides, Pd/La0.2Sr1.8-xMnO4 were prepared by liquid-phase adsorption process, and their structural and catalytic properties were investigated. Pd deposition was carried out by mixing La0.2Sr1.8MnO4 with Pd(NO3)2 in aqueous solution, followed by filtration, drying, and calcination at 800 °C. During the Pd deposition process, 5% of Sr in La0.2Sr1.8MnO4 oxides was dissolved into the aqueous phase, whereas the perovskite structure retained. The content of Pd loaded on La0.2Sr1.8MnO4 was 0.24 wt%. X-ray absorption spectroscopy studies showed that highly dispersed PdO nanoparticles were supported on Pd/La0.2Sr1.8MnO4 prepared by the liquid-phase adsorption process, whereas aggregated PdO particles were formed on Pd/La0.2Sr1.8MnO4 prepared by an impregnation method. The Pd/La0.2Sr1.8MnO4 catalyst prepared by the liquid-phase adsorption process exhibited higher catalytic activity for NO-CO reaction than the 0.24 wt% Pd/La0.2Sr1.8MnO4 catalyst prepared by the impregnation method.

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