Preparation and In-Plane Anisotropic Photobleaching Properties of Polyimide Langmuir-Blodgett Films Having a Photoresponsive p-Nitroazobenzene Pendant Group

Shiyoshi Yokoyama, Masa aki Kakimoto, Yoshio Imai

Research output: Contribution to journalArticle

25 Citations (Scopus)

Abstract

Polyamic acid 4 possessing a p-nitroazobenzene pendant group was synthesized from freshly prepared tetracarboxylic acid and 4,4′-diaminodiphenyl ether. A Langmuir-Blodgett (LB) film of the polyamic acid/long alkyl amine salt 5, which was prepared by mixing a solution of 4 with the long alkyl amine N-icosylpyrrolidine, was then prepared by a usual LB technique. Treatment of the LB film of 5 with a mixture of acetic anhydride and pyridine afforded the polyimide LB films. The UV spectrum of the polyimide exhibited a λmax of 480 nm, which suggested a trans configuration of the azobenzene unit. Isotropic orientation of the azobenzene group in a plane of the polyimide LB film was observed by using polarized UV spectroscopy. After irradiation of linearly polarized argon ion laser beam at 458 nm to the LB film, photobleaching of the azo dye at 480 nm was observed only in the direction parallel to the incident beam. The absorption ratio between parallel and perpendicular planes of the irradiated LB film was more than 2.

Original languageEnglish
Pages (from-to)1086-1091
Number of pages6
JournalLangmuir
Volume9
Issue number4
DOIs
Publication statusPublished - Jan 1 1993

Fingerprint

Photobleaching
Langmuir Blodgett films
Langmuir-Blodgett films
polyimides
Polyimides
preparation
Azobenzene
di-(4-aminophenyl)ether
acids
Amines
Acids
amines
Azo Compounds
Azo dyes
Argon
anhydrides
Ultraviolet spectroscopy
Pyridine
Laser beams
Ethers

All Science Journal Classification (ASJC) codes

  • Materials Science(all)
  • Condensed Matter Physics
  • Surfaces and Interfaces
  • Spectroscopy
  • Electrochemistry

Cite this

Preparation and In-Plane Anisotropic Photobleaching Properties of Polyimide Langmuir-Blodgett Films Having a Photoresponsive p-Nitroazobenzene Pendant Group. / Yokoyama, Shiyoshi; Kakimoto, Masa aki; Imai, Yoshio.

In: Langmuir, Vol. 9, No. 4, 01.01.1993, p. 1086-1091.

Research output: Contribution to journalArticle

@article{c7b98acd658740b8a8842a91edeaafcb,
title = "Preparation and In-Plane Anisotropic Photobleaching Properties of Polyimide Langmuir-Blodgett Films Having a Photoresponsive p-Nitroazobenzene Pendant Group",
abstract = "Polyamic acid 4 possessing a p-nitroazobenzene pendant group was synthesized from freshly prepared tetracarboxylic acid and 4,4′-diaminodiphenyl ether. A Langmuir-Blodgett (LB) film of the polyamic acid/long alkyl amine salt 5, which was prepared by mixing a solution of 4 with the long alkyl amine N-icosylpyrrolidine, was then prepared by a usual LB technique. Treatment of the LB film of 5 with a mixture of acetic anhydride and pyridine afforded the polyimide LB films. The UV spectrum of the polyimide exhibited a λmax of 480 nm, which suggested a trans configuration of the azobenzene unit. Isotropic orientation of the azobenzene group in a plane of the polyimide LB film was observed by using polarized UV spectroscopy. After irradiation of linearly polarized argon ion laser beam at 458 nm to the LB film, photobleaching of the azo dye at 480 nm was observed only in the direction parallel to the incident beam. The absorption ratio between parallel and perpendicular planes of the irradiated LB film was more than 2.",
author = "Shiyoshi Yokoyama and Kakimoto, {Masa aki} and Yoshio Imai",
year = "1993",
month = "1",
day = "1",
doi = "10.1021/la00028a034",
language = "English",
volume = "9",
pages = "1086--1091",
journal = "Langmuir",
issn = "0743-7463",
publisher = "American Chemical Society",
number = "4",

}

TY - JOUR

T1 - Preparation and In-Plane Anisotropic Photobleaching Properties of Polyimide Langmuir-Blodgett Films Having a Photoresponsive p-Nitroazobenzene Pendant Group

AU - Yokoyama, Shiyoshi

AU - Kakimoto, Masa aki

AU - Imai, Yoshio

PY - 1993/1/1

Y1 - 1993/1/1

N2 - Polyamic acid 4 possessing a p-nitroazobenzene pendant group was synthesized from freshly prepared tetracarboxylic acid and 4,4′-diaminodiphenyl ether. A Langmuir-Blodgett (LB) film of the polyamic acid/long alkyl amine salt 5, which was prepared by mixing a solution of 4 with the long alkyl amine N-icosylpyrrolidine, was then prepared by a usual LB technique. Treatment of the LB film of 5 with a mixture of acetic anhydride and pyridine afforded the polyimide LB films. The UV spectrum of the polyimide exhibited a λmax of 480 nm, which suggested a trans configuration of the azobenzene unit. Isotropic orientation of the azobenzene group in a plane of the polyimide LB film was observed by using polarized UV spectroscopy. After irradiation of linearly polarized argon ion laser beam at 458 nm to the LB film, photobleaching of the azo dye at 480 nm was observed only in the direction parallel to the incident beam. The absorption ratio between parallel and perpendicular planes of the irradiated LB film was more than 2.

AB - Polyamic acid 4 possessing a p-nitroazobenzene pendant group was synthesized from freshly prepared tetracarboxylic acid and 4,4′-diaminodiphenyl ether. A Langmuir-Blodgett (LB) film of the polyamic acid/long alkyl amine salt 5, which was prepared by mixing a solution of 4 with the long alkyl amine N-icosylpyrrolidine, was then prepared by a usual LB technique. Treatment of the LB film of 5 with a mixture of acetic anhydride and pyridine afforded the polyimide LB films. The UV spectrum of the polyimide exhibited a λmax of 480 nm, which suggested a trans configuration of the azobenzene unit. Isotropic orientation of the azobenzene group in a plane of the polyimide LB film was observed by using polarized UV spectroscopy. After irradiation of linearly polarized argon ion laser beam at 458 nm to the LB film, photobleaching of the azo dye at 480 nm was observed only in the direction parallel to the incident beam. The absorption ratio between parallel and perpendicular planes of the irradiated LB film was more than 2.

UR - http://www.scopus.com/inward/record.url?scp=0011759738&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0011759738&partnerID=8YFLogxK

U2 - 10.1021/la00028a034

DO - 10.1021/la00028a034

M3 - Article

AN - SCOPUS:0011759738

VL - 9

SP - 1086

EP - 1091

JO - Langmuir

JF - Langmuir

SN - 0743-7463

IS - 4

ER -