Preparation and reactions of trihalogeno(pentamethylcyclopentadienyl)ruthenium(IV)

Noriaki Oshima, Hiroharu Suzuki, Yoshihiko Moro-oka, Hideo Nagashima, Kenji Itoh

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28 Citations (Scopus)

Abstract

The reaction of [(C5Me5)RuCl2]m with halogen (Cl2, Br2, and I2) in dichloromethane gives trihalogenoruthenium(IV) complexes, [(C5Me5)RuX3]n (X = Cl, Br, and I), (2) in excellent yields. The RuIV complexes formulated as (C5Me5)RuX3(L) (3) are formed in the reaction of complex 2 with triphenylphosphine or carbon monoxide in dichloromethane, while treatment of complex 2 with triphenylphosphine or pyridine in ethanol exclusively affords RuIII complexes, (C5Me5)RuX2(L) (4).

Original languageEnglish
Pages (from-to)C46-C48
JournalJournal of Organometallic Chemistry
Volume314
Issue number1-2
DOIs
Publication statusPublished - Oct 21 1986
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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