Preparation and reactivity of a nickel dihydride complex

Takahiro Matsumoto, Takuma Nagahama, Jaeheung Cho, Takuhiro Hizume, Masatatsu Suzuki, Seiji Ogo

Research output: Contribution to journalArticle

21 Citations (Scopus)

Abstract

A generous donor: A dinuclear octahedral bis(μ-hydrido)dinickel(II) complex (see picture; C gray, H black, N blue, Ni green) acts as an electron donor to reduce electron acceptors such as methyl viologen. The complex is proposed as a functional model for the dihydride intermediate of an NiRu hydrogenase mimic and, by extension, of [NiFe]hydrogenase itself.

Original languageEnglish
Pages (from-to)10578-10580
Number of pages3
JournalAngewandte Chemie - International Edition
Volume50
Issue number45
DOIs
Publication statusPublished - Nov 4 2011

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Nickel
Hydrogenase
Paraquat
Electrons
nickel-iron hydrogenase

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

Cite this

Preparation and reactivity of a nickel dihydride complex. / Matsumoto, Takahiro; Nagahama, Takuma; Cho, Jaeheung; Hizume, Takuhiro; Suzuki, Masatatsu; Ogo, Seiji.

In: Angewandte Chemie - International Edition, Vol. 50, No. 45, 04.11.2011, p. 10578-10580.

Research output: Contribution to journalArticle

Matsumoto, Takahiro ; Nagahama, Takuma ; Cho, Jaeheung ; Hizume, Takuhiro ; Suzuki, Masatatsu ; Ogo, Seiji. / Preparation and reactivity of a nickel dihydride complex. In: Angewandte Chemie - International Edition. 2011 ; Vol. 50, No. 45. pp. 10578-10580.
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