Preparation and reactivity of a nickel dihydride complex

Takahiro Matsumoto, Takuma Nagahama, Jaeheung Cho, Takuhiro Hizume, Masatatsu Suzuki, Seiji Ogo

    Research output: Contribution to journalArticlepeer-review

    24 Citations (Scopus)

    Abstract

    A generous donor: A dinuclear octahedral bis(μ-hydrido)dinickel(II) complex (see picture; C gray, H black, N blue, Ni green) acts as an electron donor to reduce electron acceptors such as methyl viologen. The complex is proposed as a functional model for the dihydride intermediate of an NiRu hydrogenase mimic and, by extension, of [NiFe]hydrogenase itself.

    Original languageEnglish
    Pages (from-to)10578-10580
    Number of pages3
    JournalAngewandte Chemie - International Edition
    Volume50
    Issue number45
    DOIs
    Publication statusPublished - Nov 4 2011

    All Science Journal Classification (ASJC) codes

    • Catalysis
    • Chemistry(all)

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