Preparation of 5-trimethylsilyl-1,3-phenylenebis[diazo(4-pyridyl)methane] and magnetic properties of its 1:1 copper(II) complex after photolysis

Satoru Karasawa, Masakazu Tanaka, Noboru Koga, Hiizu Iwamura

Research output: Contribution to journalArticle

17 Citations (Scopus)

Abstract

Photolysis of a paramagnetic 1:1 complex of copper(II) with 5-trimethylsilyl-1,3-phenylenebis[diazo(4-pyridyl)methane] produces a ferromagnetic chain consisting of an alternating array of 3d spins of CuII and 2p spins of the quintet dicarbenes.

Original languageEnglish
Pages (from-to)1359-1360
Number of pages2
JournalChemical Communications
Issue number15
DOIs
Publication statusPublished - Jan 1 1997

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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