Preparation of block-copolymer-type supramolecule at liquid-liquid interface via hydrogen bonding of end groups and its aggregation structure of thin film

Mami Kawai, Daisuke Kawaguchi, Atsushi Takano, Yushu Matsushita

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

Block-copolymer-type supramolecules composed of carboxy-terminated polystyrene(PS-COOH) and amino-terminated polyethyreneoxide(PEO-NH2) were prepared in chloroform and at benzene/water interface via hydrogen-bonding interaction between end groups. Surface structures of these thin films were evaluated by atomic force microscopy(AFM). For both blend films, phase-separated structures with submicron scale were observed, meaning that there remained PS-COOH and PEO-NH2 homopolymers. Its correlation length of phase domains for the thin film prepared at benzene/water interface was 165 nm whereas that of the film prepared in chloroform solution was 255 nm. This result indicates that the block-copolymer-type supramolecules can be prepared at benzene/water interface more efficiently than in chloroform solution.

Original languageEnglish
Title of host publication55th SPSJ Symposium on Macromolecules
Pages4332-4333
Number of pages2
Volume55
Edition2
Publication statusPublished - 2006
Externally publishedYes
Event55th Society of Polymer Science Japan Symposium on Macromolecules - Toyama, Japan
Duration: Sep 20 2006Sep 22 2006

Other

Other55th Society of Polymer Science Japan Symposium on Macromolecules
CountryJapan
CityToyama
Period9/20/069/22/06

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Chlorine compounds
Block copolymers
Benzene
Hydrogen bonds
Agglomeration
Polyethylene oxides
Thin films
Liquids
Water
Phase structure
Homopolymerization
Surface structure
Atomic force microscopy
Polystyrenes

All Science Journal Classification (ASJC) codes

  • Engineering(all)

Cite this

Kawai, M., Kawaguchi, D., Takano, A., & Matsushita, Y. (2006). Preparation of block-copolymer-type supramolecule at liquid-liquid interface via hydrogen bonding of end groups and its aggregation structure of thin film. In 55th SPSJ Symposium on Macromolecules (2 ed., Vol. 55, pp. 4332-4333)

Preparation of block-copolymer-type supramolecule at liquid-liquid interface via hydrogen bonding of end groups and its aggregation structure of thin film. / Kawai, Mami; Kawaguchi, Daisuke; Takano, Atsushi; Matsushita, Yushu.

55th SPSJ Symposium on Macromolecules. Vol. 55 2. ed. 2006. p. 4332-4333.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Kawai, M, Kawaguchi, D, Takano, A & Matsushita, Y 2006, Preparation of block-copolymer-type supramolecule at liquid-liquid interface via hydrogen bonding of end groups and its aggregation structure of thin film. in 55th SPSJ Symposium on Macromolecules. 2 edn, vol. 55, pp. 4332-4333, 55th Society of Polymer Science Japan Symposium on Macromolecules, Toyama, Japan, 9/20/06.
Kawai, Mami ; Kawaguchi, Daisuke ; Takano, Atsushi ; Matsushita, Yushu. / Preparation of block-copolymer-type supramolecule at liquid-liquid interface via hydrogen bonding of end groups and its aggregation structure of thin film. 55th SPSJ Symposium on Macromolecules. Vol. 55 2. ed. 2006. pp. 4332-4333
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