Preparation of enantioenriched helical- and axial-chiral molecules by dynamic asymmetric induction

Yuya Kawasaki, Ryota Kamikubo, Yuta Kumegawa, Kouhei Ogawa, Takeru Kashiwagi, Yusuke Ano, Kazunobu Igawa, Katsuhiko Tomooka

Research output: Contribution to journalArticlepeer-review

2 Citations (Scopus)

Abstract

Dynamic asymmetric induction (DYASIN) of racemic dynamic chiral heterohelicenes afforded their highly enantioenriched forms (up to 96% ep) in quantitative yields. These heterohelicenes were readily converted into semi-static axial-chiral 1,1′-binaphthyl derivatives in a stereospecific manner.

Original languageEnglish
Pages (from-to)1605-1608
Number of pages4
JournalChemical Communications
Volume58
Issue number10
DOIs
Publication statusPublished - Feb 4 2022

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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