Abstract
We obtained three kinds of polyarylenevinylene(poly (p-phenylenevinylene), poly(2,5-dimethoxy-p-phenylenevinylene) and poly(2,5-thienylenevinylene)) thin films with the Langmuir-Blodgett (LB) technique. Stable polyarylenevinylene precursor-anionic amphiphile complex monolayers were formed at the air-precursor aqueous solution interface through adsorption of the precursors onto an amphiphilic monolayer. The polyion complex monolayers could be transferred on substrates by the LB technique. The polyarylenevinylene precursor LB films were converted to polyarylenevinylene films with a heat treatment under nitrogen flow. Extension of the mean π conjugation length and planar orientation of the π conjugation sequences were realized in the poly(p-phenylenevinylene) and poly(2,5-dimethoxy-p-phenylenevinylene) LB films.
| Original language | English |
|---|---|
| Pages (from-to) | 1-8 |
| Number of pages | 8 |
| Journal | Thin Solid Films |
| Volume | 179 |
| Issue number | 1 -2 pt 2 |
| DOIs | |
| Publication status | Published - Jan 1 1989 |
| Event | Fourth International Conference on Langmuir-Blodgett Films - Tsukuba, Jpn Duration: Apr 24 1989 → Apr 29 1989 |
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All Science Journal Classification (ASJC) codes
- Electronic, Optical and Magnetic Materials
- Surfaces and Interfaces
- Surfaces, Coatings and Films
- Metals and Alloys
- Materials Chemistry
Cite this
Preparation of highly oriented polyarylenevinylene thin films by the Langmuir-Blodgett technique. / Era, Masanao; Kamiyama, Koji; Yoshiura, Kazunori; Momii, Tatsuo; Murata, Hideyuki; Tokito, Shizuo; Tsutsui, Tetsuo; Saito, Shogo.
In: Thin Solid Films, Vol. 179, No. 1 -2 pt 2, 01.01.1989, p. 1-8.Research output: Contribution to journal › Conference article
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TY - JOUR
T1 - Preparation of highly oriented polyarylenevinylene thin films by the Langmuir-Blodgett technique
AU - Era, Masanao
AU - Kamiyama, Koji
AU - Yoshiura, Kazunori
AU - Momii, Tatsuo
AU - Murata, Hideyuki
AU - Tokito, Shizuo
AU - Tsutsui, Tetsuo
AU - Saito, Shogo
PY - 1989/1/1
Y1 - 1989/1/1
N2 - We obtained three kinds of polyarylenevinylene(poly (p-phenylenevinylene), poly(2,5-dimethoxy-p-phenylenevinylene) and poly(2,5-thienylenevinylene)) thin films with the Langmuir-Blodgett (LB) technique. Stable polyarylenevinylene precursor-anionic amphiphile complex monolayers were formed at the air-precursor aqueous solution interface through adsorption of the precursors onto an amphiphilic monolayer. The polyion complex monolayers could be transferred on substrates by the LB technique. The polyarylenevinylene precursor LB films were converted to polyarylenevinylene films with a heat treatment under nitrogen flow. Extension of the mean π conjugation length and planar orientation of the π conjugation sequences were realized in the poly(p-phenylenevinylene) and poly(2,5-dimethoxy-p-phenylenevinylene) LB films.
AB - We obtained three kinds of polyarylenevinylene(poly (p-phenylenevinylene), poly(2,5-dimethoxy-p-phenylenevinylene) and poly(2,5-thienylenevinylene)) thin films with the Langmuir-Blodgett (LB) technique. Stable polyarylenevinylene precursor-anionic amphiphile complex monolayers were formed at the air-precursor aqueous solution interface through adsorption of the precursors onto an amphiphilic monolayer. The polyion complex monolayers could be transferred on substrates by the LB technique. The polyarylenevinylene precursor LB films were converted to polyarylenevinylene films with a heat treatment under nitrogen flow. Extension of the mean π conjugation length and planar orientation of the π conjugation sequences were realized in the poly(p-phenylenevinylene) and poly(2,5-dimethoxy-p-phenylenevinylene) LB films.
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U2 - 10.1016/0040-6090(89)90157-0
DO - 10.1016/0040-6090(89)90157-0
M3 - Conference article
VL - 179
SP - 1
EP - 8
JO - Thin Solid Films
JF - Thin Solid Films
SN - 0040-6090
IS - 1 -2 pt 2
ER -