Preparation of N-grafted polyanilines utilizing ring-opening copolymerization of epoxide: Tuning of solubility and optical and electrochemical properties of polyaniline

Takuma Yasuda, Isao Yamaguchi, Takakazu Yamamoto

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

Polyanilines with various degrees of N-grafting have been synthesized by using ring-opening copolymerization of glycidyl phenyl ether (1,2-epoxy-3-phenoxypropane). The obtained polymer has good solubility in common organic solvents. Optical and thermal properties of the N-grafted polyanilines varying with the degree of the N-grafting and length of the graft side chain have been revealed. The polymer received electrochemical oxidation at about 0.40V versus Ag+/Ag in a CH3CN solution of 0.10M LiBF4.

Original languageEnglish
Pages (from-to)35-38
Number of pages4
JournalSynthetic Metals
Volume139
Issue number1
DOIs
Publication statusPublished - Aug 8 2003
Externally publishedYes

Fingerprint

epoxy compounds
Epoxy Compounds
copolymerization
Polyaniline
Electrochemical properties
Copolymerization
Polymers
solubility
Optical properties
Solubility
Tuning
tuning
optical properties
preparation
electrochemical oxidation
Electrochemical oxidation
rings
polymers
Grafts
Organic solvents

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering
  • Metals and Alloys
  • Materials Chemistry

Cite this

Preparation of N-grafted polyanilines utilizing ring-opening copolymerization of epoxide : Tuning of solubility and optical and electrochemical properties of polyaniline. / Yasuda, Takuma; Yamaguchi, Isao; Yamamoto, Takakazu.

In: Synthetic Metals, Vol. 139, No. 1, 08.08.2003, p. 35-38.

Research output: Contribution to journalArticle

@article{7c3410379844456f91d47b38d14bfd2c,
title = "Preparation of N-grafted polyanilines utilizing ring-opening copolymerization of epoxide: Tuning of solubility and optical and electrochemical properties of polyaniline",
abstract = "Polyanilines with various degrees of N-grafting have been synthesized by using ring-opening copolymerization of glycidyl phenyl ether (1,2-epoxy-3-phenoxypropane). The obtained polymer has good solubility in common organic solvents. Optical and thermal properties of the N-grafted polyanilines varying with the degree of the N-grafting and length of the graft side chain have been revealed. The polymer received electrochemical oxidation at about 0.40V versus Ag+/Ag in a CH3CN solution of 0.10M LiBF4.",
author = "Takuma Yasuda and Isao Yamaguchi and Takakazu Yamamoto",
year = "2003",
month = "8",
day = "8",
doi = "10.1016/S0379-6779(03)00080-8",
language = "English",
volume = "139",
pages = "35--38",
journal = "Synthetic Metals",
issn = "0379-6779",
publisher = "Elsevier BV",
number = "1",

}

TY - JOUR

T1 - Preparation of N-grafted polyanilines utilizing ring-opening copolymerization of epoxide

T2 - Tuning of solubility and optical and electrochemical properties of polyaniline

AU - Yasuda, Takuma

AU - Yamaguchi, Isao

AU - Yamamoto, Takakazu

PY - 2003/8/8

Y1 - 2003/8/8

N2 - Polyanilines with various degrees of N-grafting have been synthesized by using ring-opening copolymerization of glycidyl phenyl ether (1,2-epoxy-3-phenoxypropane). The obtained polymer has good solubility in common organic solvents. Optical and thermal properties of the N-grafted polyanilines varying with the degree of the N-grafting and length of the graft side chain have been revealed. The polymer received electrochemical oxidation at about 0.40V versus Ag+/Ag in a CH3CN solution of 0.10M LiBF4.

AB - Polyanilines with various degrees of N-grafting have been synthesized by using ring-opening copolymerization of glycidyl phenyl ether (1,2-epoxy-3-phenoxypropane). The obtained polymer has good solubility in common organic solvents. Optical and thermal properties of the N-grafted polyanilines varying with the degree of the N-grafting and length of the graft side chain have been revealed. The polymer received electrochemical oxidation at about 0.40V versus Ag+/Ag in a CH3CN solution of 0.10M LiBF4.

UR - http://www.scopus.com/inward/record.url?scp=0042671352&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0042671352&partnerID=8YFLogxK

U2 - 10.1016/S0379-6779(03)00080-8

DO - 10.1016/S0379-6779(03)00080-8

M3 - Article

AN - SCOPUS:0042671352

VL - 139

SP - 35

EP - 38

JO - Synthetic Metals

JF - Synthetic Metals

SN - 0379-6779

IS - 1

ER -