Preparation of novel polyimide hybrid materials by multi-layered charge-transfer complex formation

Ryohei Watari; Masamichi Nishihara; Hiroo Tajiri; Hideyuki Otsuka; Atsushi Takahara

doi:10.1038/pj.2012.222

Preparation of novel polyimide hybrid materials by multi-layered charge-transfer complex formation

Ryohei Watari, Masamichi Nishihara, Hiroo Tajiri, Hideyuki Otsuka, Atsushi Takahara

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

A versatile method for the post-modification of sulfonated polyimides by charge-transfer (CT) complex formation between electron-deficient naphthalenediimide units in polyimide and electron-rich dihydroxynaphthalene was developed. CT complex hybrid films whose physicochemical properties, such as mechanical strength, differed from those of the original polyimide films were successfully fabricated.

Original language	English
Pages (from-to)	839-844
Number of pages	6
Journal	Polymer Journal
Volume	45
Issue number	8
DOIs	https://doi.org/10.1038/pj.2012.222
Publication status	Published - Aug 2013

All Science Journal Classification (ASJC) codes

Polymers and Plastics
Materials Chemistry

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10.1038/pj.2012.222

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title = "Preparation of novel polyimide hybrid materials by multi-layered charge-transfer complex formation",

abstract = "A versatile method for the post-modification of sulfonated polyimides by charge-transfer (CT) complex formation between electron-deficient naphthalenediimide units in polyimide and electron-rich dihydroxynaphthalene was developed. CT complex hybrid films whose physicochemical properties, such as mechanical strength, differed from those of the original polyimide films were successfully fabricated.",

author = "Ryohei Watari and Masamichi Nishihara and Hiroo Tajiri and Hideyuki Otsuka and Atsushi Takahara",

note = "Funding Information: The authors acknowledge partial financial support from the International Institute for Carbon-Neutral Energy Research (WPI-I2CNER), Kyushu University, Japan. The synchrotron radiation GIWAXD measurements were performed at the BL13XU (2011A1485) in the SPring-8 with the approval of the Japan Synchrotron Radiation Research Institute (JASRI).",

year = "2013",

month = aug,

doi = "10.1038/pj.2012.222",

language = "English",

volume = "45",

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journal = "Polymer Journal",

issn = "0032-3896",

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number = "8",

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AU - Watari, Ryohei

AU - Nishihara, Masamichi

AU - Tajiri, Hiroo

AU - Otsuka, Hideyuki

AU - Takahara, Atsushi

N1 - Funding Information: The authors acknowledge partial financial support from the International Institute for Carbon-Neutral Energy Research (WPI-I2CNER), Kyushu University, Japan. The synchrotron radiation GIWAXD measurements were performed at the BL13XU (2011A1485) in the SPring-8 with the approval of the Japan Synchrotron Radiation Research Institute (JASRI).

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N2 - A versatile method for the post-modification of sulfonated polyimides by charge-transfer (CT) complex formation between electron-deficient naphthalenediimide units in polyimide and electron-rich dihydroxynaphthalene was developed. CT complex hybrid films whose physicochemical properties, such as mechanical strength, differed from those of the original polyimide films were successfully fabricated.

AB - A versatile method for the post-modification of sulfonated polyimides by charge-transfer (CT) complex formation between electron-deficient naphthalenediimide units in polyimide and electron-rich dihydroxynaphthalene was developed. CT complex hybrid films whose physicochemical properties, such as mechanical strength, differed from those of the original polyimide films were successfully fabricated.

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