Preparation of Novel Ruthenlum(IV) Complexes (η5-C5(CH3)5)Ru(η3-allyl)X2 and (η5-C5H5)Ru(η3-allyl)X2 by Oxidative Addition of Allylic Halides to Ruthenlum(II) Precursors

Hldeo Nagashima; Katsunori Mukai; Kenji Itoh

doi:10.1021/om00086a033

Preparation of Novel Ruthenlum(IV) Complexes (η⁵-C₅(CH₃)₅)Ru(η³-allyl)X₂ and (η⁵-C₅H₅)Ru(η³-allyl)X₂ by Oxidative Addition of Allylic Halides to Ruthenlum(II) Precursors

Hldeo Nagashima, Katsunori Mukai, Kenji Itoh

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

Oxidative addition of allylic halides to ruthenium(II) carbonyl complexes Cp'Ru(CO)₂X and CpRu-(CO)₂X [Cp' = η⁵-C₅(CH₃)₅; Cp = η⁵-C₅H₅; X = Br, Cl] resulted in the formation of novel Ru(IV) complexes Cp'Ru(η³-allyl)X₂ and CpRu(η³-allyl)X₂. Reaction of the resulting ruthenium(IV) allyl complexes with CO did not lead to incorporation of CO into the allylic moiety but gave rise to reductive elimination of the allylic halides from the Ru(IV) metal center to afford the ruthenium(II) carbonyl complexes Cp'-and CpRu(CO)₂X.

Original language	English
Pages (from-to)	1314-1315
Number of pages	2
Journal	Organometallics
Volume	3
Issue number	8
DOIs	https://doi.org/10.1021/om00086a033
Publication status	Published - Apr 1984
Externally published	Yes

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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10.1021/om00086a033

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@article{eb2d60895f994a41a460a8e379ba2d51,

title = "Preparation of Novel Ruthenlum(IV) Complexes (η5-C5(CH3)5)Ru(η3-allyl)X2 and (η5-C5H5)Ru(η3-allyl)X2 by Oxidative Addition of Allylic Halides to Ruthenlum(II) Precursors",

abstract = "Oxidative addition of allylic halides to ruthenium(II) carbonyl complexes Cp'Ru(CO)2X and CpRu-(CO)2X [Cp' = η5-C5(CH3)5; Cp = η5-C5H5; X = Br, Cl] resulted in the formation of novel Ru(IV) complexes Cp'Ru(η3-allyl)X2 and CpRu(η3-allyl)X2. Reaction of the resulting ruthenium(IV) allyl complexes with CO did not lead to incorporation of CO into the allylic moiety but gave rise to reductive elimination of the allylic halides from the Ru(IV) metal center to afford the ruthenium(II) carbonyl complexes Cp'-and CpRu(CO)2X.",

author = "Hldeo Nagashima and Katsunori Mukai and Kenji Itoh",

year = "1984",

month = apr,

doi = "10.1021/om00086a033",

language = "English",

volume = "3",

pages = "1314--1315",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "8",

}

TY - JOUR

T1 - Preparation of Novel Ruthenlum(IV) Complexes (η5-C5(CH3)5)Ru(η3-allyl)X2 and (η5-C5H5)Ru(η3-allyl)X2 by Oxidative Addition of Allylic Halides to Ruthenlum(II) Precursors

AU - Nagashima, Hldeo

AU - Mukai, Katsunori

AU - Itoh, Kenji

PY - 1984/4

Y1 - 1984/4

N2 - Oxidative addition of allylic halides to ruthenium(II) carbonyl complexes Cp'Ru(CO)2X and CpRu-(CO)2X [Cp' = η5-C5(CH3)5; Cp = η5-C5H5; X = Br, Cl] resulted in the formation of novel Ru(IV) complexes Cp'Ru(η3-allyl)X2 and CpRu(η3-allyl)X2. Reaction of the resulting ruthenium(IV) allyl complexes with CO did not lead to incorporation of CO into the allylic moiety but gave rise to reductive elimination of the allylic halides from the Ru(IV) metal center to afford the ruthenium(II) carbonyl complexes Cp'-and CpRu(CO)2X.

AB - Oxidative addition of allylic halides to ruthenium(II) carbonyl complexes Cp'Ru(CO)2X and CpRu-(CO)2X [Cp' = η5-C5(CH3)5; Cp = η5-C5H5; X = Br, Cl] resulted in the formation of novel Ru(IV) complexes Cp'Ru(η3-allyl)X2 and CpRu(η3-allyl)X2. Reaction of the resulting ruthenium(IV) allyl complexes with CO did not lead to incorporation of CO into the allylic moiety but gave rise to reductive elimination of the allylic halides from the Ru(IV) metal center to afford the ruthenium(II) carbonyl complexes Cp'-and CpRu(CO)2X.

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U2 - 10.1021/om00086a033

DO - 10.1021/om00086a033

M3 - Article

AN - SCOPUS:0000853855

SN - 0276-7333

VL - 3

SP - 1314

EP - 1315

JO - Organometallics

JF - Organometallics

IS - 8

ER -

Preparation of Novel Ruthenlum(IV) Complexes (η⁵-C₅(CH₃)₅)Ru(η³-allyl)X₂ and (η⁵-C₅H₅)Ru(η³-allyl)X₂ by Oxidative Addition of Allylic Halides to Ruthenlum(II) Precursors

Abstract

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