Preparation of optically active (R)- and (S)-allene-1,3-dicarboxylates and their asymmetric cycloaddition reactions with cyclopentadiene

Mariko Aso, Izumi Ikeda, Tsuyoshi Kawabe, Motoo Shiro, Ken Kanematsu

Research output: Contribution to journalArticle

24 Citations (Scopus)

Abstract

Optically active (R)- and (S)- allene-1,3-dicarboxylates were prepared, and their asymmetric Diels-Alder reactions with cyclopentadiene in the presence of Lewis acid proceeded to afford the endo-adducts in high yields.

Original languageEnglish
Pages (from-to)5787-5790
Number of pages4
JournalTetrahedron Letters
Volume33
Issue number39
DOIs
Publication statusPublished - Sep 22 1992

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Cyclopentanes
Lewis Acids
Cycloaddition
Cycloaddition Reaction
propadiene

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

Cite this

Preparation of optically active (R)- and (S)-allene-1,3-dicarboxylates and their asymmetric cycloaddition reactions with cyclopentadiene. / Aso, Mariko; Ikeda, Izumi; Kawabe, Tsuyoshi; Shiro, Motoo; Kanematsu, Ken.

In: Tetrahedron Letters, Vol. 33, No. 39, 22.09.1992, p. 5787-5790.

Research output: Contribution to journalArticle

Aso, Mariko ; Ikeda, Izumi ; Kawabe, Tsuyoshi ; Shiro, Motoo ; Kanematsu, Ken. / Preparation of optically active (R)- and (S)-allene-1,3-dicarboxylates and their asymmetric cycloaddition reactions with cyclopentadiene. In: Tetrahedron Letters. 1992 ; Vol. 33, No. 39. pp. 5787-5790.
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