Preparation of polymer brushes with well-controlled stereoregularity and evaluation of their functional properties

Tomoyasu Hirai, Masanao Sato, Tomoki Kato, Hitoshi Shimamoto, Kiyu Uno, Nobuyuki Otozawa, Atsushi Takahara

Research output: Contribution to journalReview article

Abstract

Polymer brushes in which one polymer chain end is tethered to a substrate show permanent properties related to the chemical structure of the polymer. However, they cannot accommodate functional molecules in the desired space because of the steric hindrance between neighboring polymer chains. To overcome this problem, the preparation of polymer brushes with ordered nanopores is strongly desired. High-density poly(methyl methacrylate) brushes with well-controlled stereoregularity were prepared using a surface-initiated living anionic polymerization method in the presence of a Lewis acid. A molecular weight range from 6 to 400 K with a narrow polydispersity index was obtained. Grazing incidence wide-angle X-ray diffraction measurements indicated that the polymer brushes formed a helical structure approximately 1 nm in diameter and consisting of encapsulated functional molecules or polymers, leading to the formation of inclusion complexes or stereocomplexes.

Original languageEnglish
Pages (from-to)931-939
Number of pages9
JournalPolymer Journal
Volume50
Issue number10
DOIs
Publication statusPublished - Oct 1 2018

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Brushes
Polymers
Lewis Acids
Molecules
Living polymerization
Anionic polymerization
Nanopores
Polydispersity
Polymethyl Methacrylate
Polymethyl methacrylates
Molecular weight
X ray diffraction
Acids
Substrates

All Science Journal Classification (ASJC) codes

  • Polymers and Plastics
  • Materials Chemistry

Cite this

Preparation of polymer brushes with well-controlled stereoregularity and evaluation of their functional properties. / Hirai, Tomoyasu; Sato, Masanao; Kato, Tomoki; Shimamoto, Hitoshi; Uno, Kiyu; Otozawa, Nobuyuki; Takahara, Atsushi.

In: Polymer Journal, Vol. 50, No. 10, 01.10.2018, p. 931-939.

Research output: Contribution to journalReview article

Hirai, Tomoyasu ; Sato, Masanao ; Kato, Tomoki ; Shimamoto, Hitoshi ; Uno, Kiyu ; Otozawa, Nobuyuki ; Takahara, Atsushi. / Preparation of polymer brushes with well-controlled stereoregularity and evaluation of their functional properties. In: Polymer Journal. 2018 ; Vol. 50, No. 10. pp. 931-939.
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