Preparation of polythiophene microrods with ordered chain alignment using nanoporous coordination template

Takashi Kitao; Michael W.A. MacLean; Benjamin Le Ouay; Yotaro Sasaki; Masahiko Tsujimoto; Susumu Kitagawa; Takashi Uemura

doi:10.1039/c7py00309a

Preparation of polythiophene microrods with ordered chain alignment using nanoporous coordination template

Takashi Kitao, Michael W.A. MacLean, Benjamin Le Ouay, Yotaro Sasaki, Masahiko Tsujimoto, Susumu Kitagawa, Takashi Uemura

Research output: Contribution to journal › Article › peer-review

22 Citations (Scopus)

Abstract

The properties of polymeric materials can be amplified by macromolecular alignment. The highly ordered chain alignment of unsubstituted polythiophene, an unprocessable polymer, has been achieved using a porous coordination polymer (PCP) as a template. Due to the extended conjugation system, the obtained anisotropic polymer particles exhibit higher conductivity than that of polythiophene prepared by solution polymerization.

Original language	English
Pages (from-to)	5077-5081
Number of pages	5
Journal	Polymer Chemistry
Volume	8
Issue number	34
DOIs	https://doi.org/10.1039/c7py00309a
Publication status	Published - Sep 14 2017
Externally published	Yes

All Science Journal Classification (ASJC) codes

Bioengineering
Biochemistry
Polymers and Plastics
Organic Chemistry

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10.1039/c7py00309a

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Preparation of polythiophene microrods with ordered chain alignment using nanoporous coordination template. / Kitao, Takashi; MacLean, Michael W.A.; Le Ouay, Benjamin; Sasaki, Yotaro; Tsujimoto, Masahiko; Kitagawa, Susumu; Uemura, Takashi.

In: Polymer Chemistry, Vol. 8, No. 34, 14.09.2017, p. 5077-5081.

Research output: Contribution to journal › Article › peer-review

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abstract = "The properties of polymeric materials can be amplified by macromolecular alignment. The highly ordered chain alignment of unsubstituted polythiophene, an unprocessable polymer, has been achieved using a porous coordination polymer (PCP) as a template. Due to the extended conjugation system, the obtained anisotropic polymer particles exhibit higher conductivity than that of polythiophene prepared by solution polymerization.",

author = "Takashi Kitao and MacLean, {Michael W.A.} and {Le Ouay}, Benjamin and Yotaro Sasaki and Masahiko Tsujimoto and Susumu Kitagawa and Takashi Uemura",

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AU - Kitao, Takashi

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AU - Le Ouay, Benjamin

AU - Sasaki, Yotaro

AU - Tsujimoto, Masahiko

AU - Kitagawa, Susumu

AU - Uemura, Takashi

N1 - Funding Information: This work was supported by CREST-JST and a Grant-in-Aid for Scientific Research on Innovative Area “Coordination Asymmetry (No. 2802)” from the Ministry of Education, Culture, Sports, Science and Technology, Government of Japan. Publisher Copyright: This journal is © The Royal Society of Chemistry.

PY - 2017/9/14

Y1 - 2017/9/14

N2 - The properties of polymeric materials can be amplified by macromolecular alignment. The highly ordered chain alignment of unsubstituted polythiophene, an unprocessable polymer, has been achieved using a porous coordination polymer (PCP) as a template. Due to the extended conjugation system, the obtained anisotropic polymer particles exhibit higher conductivity than that of polythiophene prepared by solution polymerization.

AB - The properties of polymeric materials can be amplified by macromolecular alignment. The highly ordered chain alignment of unsubstituted polythiophene, an unprocessable polymer, has been achieved using a porous coordination polymer (PCP) as a template. Due to the extended conjugation system, the obtained anisotropic polymer particles exhibit higher conductivity than that of polythiophene prepared by solution polymerization.

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Preparation of polythiophene microrods with ordered chain alignment using nanoporous coordination template

Abstract

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