Preparation of Pt/Rh bimetallic colloidal particles in polymer solutions using borohydride-reduction

Masafumi Harada, Hisahiro Einaga

Research output: Contribution to journalArticlepeer-review

31 Citations (Scopus)

Abstract

Colloidal dispersions of Pt/Rh bimetallic particles have been synthesized by the reduction of Pt(IV)/Rh(III) ionic solutions by using borohydride-reduction in the presence of poly(N-vinyl-2-pyrrolidone). The size and the structure of the synthesized particles have been examined by transmission electron micrograph (TEM) and extended X-ray absorption fine structure (EXAFS). We have succeeded in producing the bimetallic Pt/Rh particles with an average diameter of 2.8 nm in polymer solutions by the stepwise addition of sodium borohydride aqueous solution. The distribution of different metallic species in a particle tended to be "cluster-in-cluster" structure, in contrast to the bimetallic particle with an average diameter of 1.4 nm synthesized by alcohol-reduction which have a core-shell structure.

Original languageEnglish
Pages (from-to)568-572
Number of pages5
JournalJournal of Colloid And Interface Science
Volume308
Issue number2
DOIs
Publication statusPublished - Apr 15 2007

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Biomaterials
  • Surfaces, Coatings and Films
  • Colloid and Surface Chemistry

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