Preparation of TiO2 hollow-fibers using supramolecular assemblies

Satoshi Kobayashi, Kenji Hanabusa, Nobuhiro Hamasaki, Mutsumi Kimura, Hirofusa Shirai, Seiji Shinkai

Research output: Contribution to journalArticle

259 Citations (Scopus)

Abstract

trans-(1R,2R)-1,2-Cyclohexanedi(11-aminocarbonylundecylpyridinium) hexafluorophosphate (1) was synthesized. The sol-gel polymerization of Ti[OCH(CH3)2]4 using compound 1 as a self-assembled template afforded fibrous TiO2 materials with a 'macaroni'-like structure. The unique structure of TiO2 could be created by the formation of a fibrous self-assembled aggregate and electrostatic interaction between anionic titania species and cationic 1 under basic conditions.

Original languageEnglish
Pages (from-to)1523-1525
Number of pages3
JournalChemistry of Materials
Volume12
Issue number6
DOIs
Publication statusPublished - Jun 1 2000
Externally publishedYes

Fingerprint

Coulomb interactions
Sol-gels
Titanium
Polymerization
Fibers
titanium dioxide

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Chemical Engineering(all)
  • Materials Chemistry

Cite this

Kobayashi, S., Hanabusa, K., Hamasaki, N., Kimura, M., Shirai, H., & Shinkai, S. (2000). Preparation of TiO2 hollow-fibers using supramolecular assemblies. Chemistry of Materials, 12(6), 1523-1525. https://doi.org/10.1021/cm0000907

Preparation of TiO2 hollow-fibers using supramolecular assemblies. / Kobayashi, Satoshi; Hanabusa, Kenji; Hamasaki, Nobuhiro; Kimura, Mutsumi; Shirai, Hirofusa; Shinkai, Seiji.

In: Chemistry of Materials, Vol. 12, No. 6, 01.06.2000, p. 1523-1525.

Research output: Contribution to journalArticle

Kobayashi, S, Hanabusa, K, Hamasaki, N, Kimura, M, Shirai, H & Shinkai, S 2000, 'Preparation of TiO2 hollow-fibers using supramolecular assemblies', Chemistry of Materials, vol. 12, no. 6, pp. 1523-1525. https://doi.org/10.1021/cm0000907
Kobayashi S, Hanabusa K, Hamasaki N, Kimura M, Shirai H, Shinkai S. Preparation of TiO2 hollow-fibers using supramolecular assemblies. Chemistry of Materials. 2000 Jun 1;12(6):1523-1525. https://doi.org/10.1021/cm0000907
Kobayashi, Satoshi ; Hanabusa, Kenji ; Hamasaki, Nobuhiro ; Kimura, Mutsumi ; Shirai, Hirofusa ; Shinkai, Seiji. / Preparation of TiO2 hollow-fibers using supramolecular assemblies. In: Chemistry of Materials. 2000 ; Vol. 12, No. 6. pp. 1523-1525.
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